Outputs (3)

Unlocking same‐sign CPL: solvent effects on spectral form and racemisation kinetics in nine‐coordinate chiral europium(III) complexes (2023)
Journal Article
De Rosa, D. F., Starck, M., Parker, D., & Pal, R. (2023). Unlocking same‐sign CPL: solvent effects on spectral form and racemisation kinetics in nine‐coordinate chiral europium(III) complexes. Chemistry - A European Journal, https://doi.org/10.1002/chem.202303227

Understanding the factors that shape the circularly polarised luminescence (CPL) emission profiles of europium(III)-based CPL emitters to have specific sign properties, e. g. monosignate individual CPL transitions, is key to design novel complexes fo... Read More about Unlocking same‐sign CPL: solvent effects on spectral form and racemisation kinetics in nine‐coordinate chiral europium(III) complexes.

Two-Photon Circularly Polarized Luminescence of Chiral Eu Complexes (2023)
Journal Article
Willis, O. G., Petri, F., De Rosa, D. F., Mandoli, A., Pal, R., Zinna, F., & Di Bari, L. (2023). Two-Photon Circularly Polarized Luminescence of Chiral Eu Complexes. Journal of the American Chemical Society, 145(46), 25170-25176. https://doi.org/10.1021/jacs.3c05957

We report the synthesis of chiral lanthanide complexes with extended π conjugation for efficient circularly polarized luminescence (CPL) via two-photon excitation (2PE). The pyridine bis-oxazoline (PyBox) core provides the chiral Ln3+ environment, wh... Read More about Two-Photon Circularly Polarized Luminescence of Chiral Eu Complexes.

Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences (2023)
Journal Article
De Rosa, D. F., Brook, P., Black, D. J., & Pal, R. (2023). Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences. Nature Communications, 14, Article 1537. https://doi.org/10.1038/s41467-023-37329-8

Circularly polarised luminescence (CPL) is gaining a rapidly increasing following and finding new applications in both life and material sciences. Spurred by recent instrumental advancements, the development of CPL active chiral emitters is going thr... Read More about Rapid handheld time-resolved circularly polarised luminescence photography camera for life and material sciences.