Phosphanyl Methanimine (PCN) Ligands for the Selective Trimerization/Tetramerization of Ethylene with Chromium
(2015)
Journal Article
Radcliffe, J. E., Batsanov, A. S., Smith, D. M., Scott, J. A., Dyer, P. W., & Hanton, M. J. (2015). Phosphanyl Methanimine (PCN) Ligands for the Selective Trimerization/Tetramerization of Ethylene with Chromium. ACS Catalysis, 5(12), 7095-7098. https://doi.org/10.1021/acscatal.5b02106
1-Phosphanyl methanimine ligands, R2P–C(Ph)═NR′, may be prepared via a modular, convergent synthesis in good overall yield. Coordination chemistry studies with chromium confirm that they bind in a bidentate κ2-P,N mode. In combination with chromium a... Read More about Phosphanyl Methanimine (PCN) Ligands for the Selective Trimerization/Tetramerization of Ethylene with Chromium.