Oligo(aryleneethynylene)s with Terminal Pyridyl Groups: Synthesis and Length Dependence of the Tunnelling to Hopping Transition in Single-Molecule Conductances
(2013)
Journal Article
Zhao, X., Huang, C., Gulcur, M., Batsanov, A. S., Baghernejad, M., Hong, W., …Wandlowski, T. (2013). Oligo(aryleneethynylene)s with Terminal Pyridyl Groups: Synthesis and Length Dependence of the Tunnelling to Hopping Transition in Single-Molecule Conductances. Chemistry of Materials, 25(21), 4340-4347. https://doi.org/10.1021/cm4029484
The synthesis is reported of a new series of oligo(aryleneethynylene) (OAE) derivatives of up to ca. 6 nm in molecular length (OAE9) using iterative Pd-mediated Sonogashira cross-coupling methodology. The oligo-p-phenyleneethynylene cores of the mole... Read More about Oligo(aryleneethynylene)s with Terminal Pyridyl Groups: Synthesis and Length Dependence of the Tunnelling to Hopping Transition in Single-Molecule Conductances.