All Outputs (3)

Pentafluorophenylphosphine complexes of Rhodium(I): Extended x-rayabsorption fine structure studies of[{Rh[PPh(x)(C6F5)(3-x)](2)(mu-Cl)}(n)] (x=0-2) and[{Rh[(C6F5)(2)PCH2CH2P(C6F5)(2)](mu-Cl)}(2)]. Crystal structures of[RhCl(PPh(3)){(C6F5)(2)PCH2CH2P(C6F5 (1995)
Journal Article
Atherton, M., Coleman, K., Fawcett, J., Holloway, J., Hope, E., Karacar, A., …Saunders, G. (1995). Pentafluorophenylphosphine complexes of Rhodium(I): Extended x-rayabsorption fine structure studies of[{Rh[PPh(x)(C6F5)(3-x)](2)(mu-Cl)}(n)] (x=0-2) and[{Rh[(C6F5)(2)PCH2CH2P(C6F5)(2)](mu-Cl)}(2)]. Crystal structures of[RhCl(PPh(3)){(C6F5)(2)PCH2CH2P(C6F5. Journal of the Chemical Society. Dalton transactions, 4029-4037

The NMR spectroscopic properties of the rhodium pentafluorophenylphosphine complexes [{Rh[PPh(x)(C6F5)(3-x)](2)(mu-Cl)}(n)] (x = 0 1, 1 2 or 2 3) and trans-[Rh{PPh(x)(C6F5)(3-x)}Cl-2(CO)] (x = 0 5, 1 6 or 2 7) have been investigated. The new complexe... Read More about Pentafluorophenylphosphine complexes of Rhodium(I): Extended x-rayabsorption fine structure studies of[{Rh[PPh(x)(C6F5)(3-x)](2)(mu-Cl)}(n)] (x=0-2) and[{Rh[(C6F5)(2)PCH2CH2P(C6F5)(2)](mu-Cl)}(2)]. Crystal structures of[RhCl(PPh(3)){(C6F5)(2)PCH2CH2P(C6F5.

Tris(2,6-Difluorophenyl)phosphite complexes of platinum group metals -Structure of trans-PtCl2(PEt(3))(P(O-2,6-C6H3F2)(3)) (1995)
Journal Article
Coleman, K., Holloway, J., Hope, E., Russell, D., & Saunders, G. (1995). Tris(2,6-Difluorophenyl)phosphite complexes of platinum group metals -Structure of trans-PtCl2(PEt(3))(P(O-2,6-C6H3F2)(3)). Polyhedron, 14(15-16), 2107-2113

The reactions between the fluorine-containing ligand tris(2,6-difluorophenyl)phosphite and the transition metal species [{eta(6)-1,4-CH3C6H4CH(CH3)(2)} RuCl2](2), [Cp*RhCl2](2), [RhCl(CO)(2)](2), [PtCl2(PEt(3))](2) and PtCl2 yield the complexes {eta(... Read More about Tris(2,6-Difluorophenyl)phosphite complexes of platinum group metals -Structure of trans-PtCl2(PEt(3))(P(O-2,6-C6H3F2)(3)).

Ruthenium and osmium acyl fluoride complexes - Crystal structure of [OC-6-13][RUF2(CO)(2)(PPh(3))].CD2Cl(2) (1995)
Journal Article
Brewer, S., Coleman, K., Fawcett, J., Holloway, J., Hope, E., Russell, D., & Watson, P. (1995). Ruthenium and osmium acyl fluoride complexes - Crystal structure of [OC-6-13][RUF2(CO)(2)(PPh(3))].CD2Cl(2). Journal of the Chemical Society. Dalton transactions (2001. Online), 1073-1076. https://doi.org/10.1039/dt9950001073

Fluoroacyl complexes of ruthenium and osmium have been identified in the oxidative addition of XeF2 to [M(CO)(3)(PPh(3))(2)] (M = Ru or Os) in dichloromethane. The mechanism of reaction, probed by the addition of BF3, involves oxidation of the metal... Read More about Ruthenium and osmium acyl fluoride complexes - Crystal structure of [OC-6-13][RUF2(CO)(2)(PPh(3))].CD2Cl(2).