Professor Karl Coleman k.s.coleman@durham.ac.uk
Academic Visitor
Tris(2,6-Difluorophenyl)phosphite complexes of platinum group metals -Structure of trans-PtCl2(PEt(3))(P(O-2,6-C6H3F2)(3))
Coleman, KS; Holloway, JH; Hope, EG; Russell, DR; Saunders, GC
Authors
JH Holloway
EG Hope
DR Russell
GC Saunders
Abstract
The reactions between the fluorine-containing ligand tris(2,6-difluorophenyl)phosphite and the transition metal species [{eta(6)-1,4-CH3C6H4CH(CH3)(2)} RuCl2](2), [Cp*RhCl2](2), [RhCl(CO)(2)](2), [PtCl2(PEt(3))](2) and PtCl2 yield the complexes {eta(6)-1,4-CH3C6H4CH(CH3)(2)} RuCl2{P(O-2,6-C6H3F2)(3)}, Cp*RhCl2{P(O-2,6-C6H3F2)(3)}, trans-RhCl(CO {P(O-2,6-C6H3F2)(3)}(2), trans-PtCl2 (PEt(3)) {PO-2,6-C6H3F2)(3)} and trans-PtCl2{P(O-2,6-C6H3F2)(3)}(2), respectively. The molecular structure of trans-PtCl2(PEt(3)) {P(O-2,6-C6H3F2)(3)} has been determined by single-crystal X-ray crystallography.
Citation
Coleman, K., Holloway, J., Hope, E., Russell, D., & Saunders, G. (1995). Tris(2,6-Difluorophenyl)phosphite complexes of platinum group metals -Structure of trans-PtCl2(PEt(3))(P(O-2,6-C6H3F2)(3)). Polyhedron, 14(15-16), 2107-2113
Journal Article Type | Article |
---|---|
Publication Date | 1995-08 |
Journal | Polyhedron |
Print ISSN | 0277-5387 |
Electronic ISSN | 1873-3719 |
Publisher | Elsevier |
Peer Reviewed | Peer Reviewed |
Volume | 14 |
Issue | 15-16 |
Pages | 2107-2113 |
Keywords | Phosphines; Platinum |
Public URL | https://durham-repository.worktribe.com/output/1553442 |
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