Controlling the variation of axial water exchange rates in macrocyclic lanthanide(III) complexes

Aime, S.; Barge, A.; Batsanov, A.S.; Botta, M.; Castelli, D.D.; Fedeli, F.; Mortillaro, A.; Parker, D.; Puschmann, H.

Abstract

The rate of axial water exchange in well-defined series of lanthanide complexes depends on the extent of second sphere hydration which is determined by complex hydrophobicity and the nature of the lanthanide ion and its counter-ion.

Citation

Aime, S., Barge, A., Batsanov, A., Botta, M., Castelli, D., Fedeli, F., …Puschmann, H. (2002). Controlling the variation of axial water exchange rates in macrocyclic lanthanide(III) complexes. Chemical Communications, 1120-1121

• Journal Article Type: Article
• Publication Date: 2002
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Issue: 10
• Pages: 1120-1121