Coordination properties of a 2-aryl-1,3,2-dioxaphospholane

Coffer, Philippa K.; Dillon, Keith B.; Howard, Judith A.K.; Probert, Michael R.; Shepherd, Helena J.

Abstract

The coordination properties of the 2-aryl-1,3,2-dioxaphospholane 2,6-(CF3)2C6H3P(OCH2)21 (L) have been investigated, by reaction with elemental selenium in solution to form the phosphorus(V) oxidation product 2,6-(CF3)2C6H3P(Se)(OCH2)22, and with metal-containing precursors to form three new complexes trans-[PdCl(μ-Cl)(L)]23, cis-[PdMe2L2] 4 and [AuCl(L)] 5. All of the metal complexes have been characterised by single-crystal X-ray structure determination.

Citation

Coffer, P. K., Dillon, K. B., Howard, J. A., Probert, M. R., & Shepherd, H. J. (2018). Coordination properties of a 2-aryl-1,3,2-dioxaphospholane. Inorganica Chimica Acta, 479, 24-29. https://doi.org/10.1016/j.ica.2018.04.030

• Journal Article Type: Article
• Acceptance Date: Apr 18, 2018
• Online Publication Date: Apr 20, 2018
• Publication Date: Apr 20, 2018
• Deposit Date: May 18, 2018
• Publicly Available Date: Apr 20, 2019
• Journal: Inorganica Chimica Acta
• Print ISSN: 0020-1693
• Publisher: Elsevier
• Peer Reviewed: Peer Reviewed
• Volume: 479
• Pages: 24-29
• DOI: https://doi.org/10.1016/j.ica.2018.04.030