Tetrakis 3,5-bis-(trifluoromethyl)phenyl silane

Agnew, C.; Dillon, K.B.; Goeta, A.E.; Thompson, A.L.

Abstract

The title compound, tetra­kis[3,5-bis­(trifluoro­meth­yl)phen­yl]silane (SiAr'''4, C32H12F24Si), is a minor product from the reaction of silicon(IV) bromide with lithia­ted 1,3-bis­(trifluoro­meth­yl)benzene (Ar'H). The structure crystallizes with two half-mol­ecules in the asymmetric unit, with each central Si atom positioned on a twofold axis in a pseudo-tetra­hedral environment, with Si-C bond lengths in the range 1.873 (3)-1.879 (3) Å.

Citation

Agnew, C., Dillon, K., Goeta, A., & Thompson, A. (2006). Tetrakis 3,5-bis-(trifluoromethyl)phenyl silane. Acta crystallographica. Section E, 62, o2344-o2346. https://doi.org/10.1107/s1600536806017417

• Journal Article Type: Article
• Publication Date: 2006
• Journal: Acta crystallographica. Section E, Structure reports online.
• Electronic ISSN: 1600-5368
• Publisher: International Union of Crystallography
• Peer Reviewed: Peer Reviewed
• Volume: 62
• Pages: o2344-o2346
• DOI: https://doi.org/10.1107/s1600536806017417
• Public URL: https://durham-repository.worktribe.com/output/1541795