New group 15 compounds containing the 2,4,6-(CF3)(3)C6H2(fluoromes = Ar), 2,6-(CF3)(2)C6H3 (fluoroxyl = Ar ') or 2,4-(CF3)(2)C6H3 (Ar '') ligands

Batsanov, A.S.; Cornet, S.M.; Dillon, K.B.; Goeta, A.E.; Hazendonk, P.; Thompson, A.L.

Abstract

Several new P or As compounds containing the 2,4,6-(CF3)(3)C6H2 (Ar), 2,6-(CF3)(2)C6H3 (Ar') and/or 2,4-(CF3)(2)C6H3 (Ar") ligands have been synthesised, and characterised by multinuclear NMR spectroscopy and (for all isolated compounds) elemental analysis. The crystal and molecular structures of ArPBr2 1, Ar2PCl 2, Ar-2"PCl3, Ar-2" PBr 4, Ar'Ar"AsCl 5, Ar'Ar"AsBr 6 and Ar'Ar"AsH 7 have been determined by single-crystal X-ray diffraction. A particularly interesting feature of these structures is close contacts between ortho-fluorines and the P or As atoms, as observed previously in Ar'Ar"PCl and Ar2AsCl.

Citation

Batsanov, A., Cornet, S., Dillon, K., Goeta, A., Hazendonk, P., & Thompson, A. (2002). New group 15 compounds containing the 2,4,6-(CF3)(3)C6H2(fluoromes = Ar), 2,6-(CF3)(2)C6H3 (fluoroxyl = Ar ') or 2,4-(CF3)(2)C6H3 (Ar '') ligands. Dalton Transactions, 24, 4622-4628. https://doi.org/10.1039/b207327g

• Journal Article Type: Article
• Publication Date: 2002-11
• Deposit Date: Apr 12, 2007
• Journal: Dalton Transactions
• Print ISSN: 1477-9226
• Electronic ISSN: 1477-9234
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 24
• Pages: 4622-4628
• DOI: https://doi.org/10.1039/b207327g
• Public URL: https://durham-repository.worktribe.com/output/1571926