Marcus J. Giansiracusa
Determination of molecular hydration in solution via changes in magnetic anisotropy
Giansiracusa, Marcus J.; Vonci, Michele; Whyatt, Yasmin L.; Williams, Carys; Mason, Kevin; Parker, David; McInnes, Eric J.L.; Chilton, Nicholas F.
Authors
Michele Vonci
Yasmin L. Whyatt
Carys Williams
Kevin Mason
Dr David Parker dave.parker@durham.ac.uk
Experimental Officer
Eric J.L. McInnes
Nicholas F. Chilton
Abstract
The hydration behaviour of coordination complexes is important for understanding their roles as bio-imaging agents. Determination of hydration is difficult, and various optical and NMR-based techniques have been used. Here we use EPR spectroscopy to unambiguously demonstrate that a t-butyl-pyridyl-functionalised ErIII DOTA derivative coordinates water, while its methylphosphinate analogue does not.
Citation
Giansiracusa, M. J., Vonci, M., Whyatt, Y. L., Williams, C., Mason, K., Parker, D., …Chilton, N. F. (2023). Determination of molecular hydration in solution via changes in magnetic anisotropy. Chemical Communications, 59(30), 4531-4534. https://doi.org/10.1039/d3cc00601h
Journal Article Type | Article |
---|---|
Acceptance Date | Mar 20, 2023 |
Online Publication Date | Mar 20, 2023 |
Publication Date | 2023 |
Deposit Date | May 3, 2023 |
Publicly Available Date | May 3, 2023 |
Journal | Chemical Communications |
Print ISSN | 1359-7345 |
Electronic ISSN | 1364-548X |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
Volume | 59 |
Issue | 30 |
Pages | 4531-4534 |
DOI | https://doi.org/10.1039/d3cc00601h |
Public URL | https://durham-repository.worktribe.com/output/1175300 |
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Copyright Statement
Open Access. This article is distributed under the terms of the Creative Commons Attribution License (CC-BY 3.0), which permits any use, distribution and reproduction in any medium, provided the original author(s) and source are credited.
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