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Argentophilicity-Dependent Colossal Thermal Expansion in Extended Prussian Blue Analogues. (2008)
Journal Article
Goodwin, A. L., Keen, D. A., Tucker, M. G., Dove, M. T., Peters, L., & Evans, J. S. (2008). Argentophilicity-Dependent Colossal Thermal Expansion in Extended Prussian Blue Analogues. Journal of the American Chemical Society, 130(30), 9660-9661. https://doi.org/10.1021/ja803623u

The thermal expansion behavior of isostructural variants of the colossal thermal expansion material Ag3[CoIII(CN)6] has been investigated using variable temperature X-ray and neutron powder diffraction. It was found that substitution at the octahedra... Read More about Argentophilicity-Dependent Colossal Thermal Expansion in Extended Prussian Blue Analogues..

Polymorphism and hydrogen bonding in cinchomeronic acid: a variable temperature experimental and computational study (2008)
Journal Article
Evans, I. R., Howard, J. A., Evans, J. S., Postlethwaite, S. R., & Johnson, M. R. (2008). Polymorphism and hydrogen bonding in cinchomeronic acid: a variable temperature experimental and computational study. CrystEngComm, 10(10), 1404-1409. https://doi.org/10.1039/b807015f

3,4-Pyridinedicarboxylic acid is a compound commonly used as a multifunctional ligand in coordination chemistry. The crystal structure of its orthorhombic Form I has been known for over 30 years, while a new Form II has only been reported recently as... Read More about Polymorphism and hydrogen bonding in cinchomeronic acid: a variable temperature experimental and computational study.

Structural ferroelectric phase transition and polymorphism in 2-aminopyridine dihydrogen phosphate (2008)
Journal Article
Evans, I. R., Howard, J. A., & Evans, J. S. (2008). Structural ferroelectric phase transition and polymorphism in 2-aminopyridine dihydrogen phosphate. Crystal Growth and Design, 8(5), 1635-1639. https://doi.org/10.1021/cg701076s

The structural ferroelectric phase transition in 2-aminopyridine dihydrogen phosphate (2APP) has been studied by single crystal and powder X-ray diffraction between room temperature and 16 K. It has been shown that α-aminopyridine dihydrogen phosphat... Read More about Structural ferroelectric phase transition and polymorphism in 2-aminopyridine dihydrogen phosphate.

Local structure in Ag3[Co(CN)6]: colossal thermal expansion, rigid unit modes and argentophilic interactions (2008)
Journal Article
Conterio, M. J., Goodwin, A. L., Tucker, M. G., Keen, D. A., Dove, M. T., Peters, L., & Evans, J. S. (2008). Local structure in Ag3[Co(CN)6]: colossal thermal expansion, rigid unit modes and argentophilic interactions. Journal of Physics: Condensed Matter, 20(25), Article 255225. https://doi.org/10.1088/0953-8984/20/25/255225

Local structure in the colossal thermal expansion material Ag3[Co(CN)6] is studied here using a combination of neutron total scattering and reverse Monte Carlo (RMC) analysis. We show that the large thermal variations in cell dimensions occur with mi... Read More about Local structure in Ag3[Co(CN)6]: colossal thermal expansion, rigid unit modes and argentophilic interactions.

Colossal Positive and Negative Thermal Expansion in the Framework Material Ag3[Co(CN)6] (2008)
Journal Article
Goodwin, A., Calleja, M., Conterio, M., Dove, M., Evans, J., Keen, D., …Tucker, M. (2008). Colossal Positive and Negative Thermal Expansion in the Framework Material Ag3[Co(CN)6]. Science, 319(5864), 794-797. https://doi.org/10.1126/science.1151442

We show that silver(I) hexacyanocobaltate(III), Ag3[Co(CN)6], exhibits positive and negative thermal expansion an order of magnitude greater than that seen in other crystalline materials. This framework material expands along one set of directions at... Read More about Colossal Positive and Negative Thermal Expansion in the Framework Material Ag3[Co(CN)6].

Structural chemistry of (PPh4)2M(WS4)2 materials. (2008)
Journal Article
Crossland, C. J., Evans, I. R., & Evans, J. S. (2008). Structural chemistry of (PPh4)2M(WS4)2 materials. Dalton Transactions, 1597-1601. https://doi.org/10.1039/b716407f

In this paper we discuss the structural chemistry of (PPh4)2M(WS4)2 (M = Co, Ni, Zn) materials. For M = Ni we and others have been unable to grow single crystals and we report the structure determination from powder diffraction. The material is tricl... Read More about Structural chemistry of (PPh4)2M(WS4)2 materials..