Skip to main content

Research Repository

Advanced Search

All Outputs (3)

Self-diffusion and viscoelastic measurements of polystyrene star polymers. (2005)
Journal Article
Clarke, N., Colley, F., Collins, S., Hutchings, L., & Thompson, R. (2005). Self-diffusion and viscoelastic measurements of polystyrene star polymers. Macromolecules, 39(3), 1290-1296. https://doi.org/10.1021/ma051973s

A series of hydrogenous and deuterated four-arm polystyrene stars with low polydispersity have been synthesized by anionic polymerization. Self-diffusion data have been obtained using helium-3 nuclear reaction analysis, and rheology has been employed... Read More about Self-diffusion and viscoelastic measurements of polystyrene star polymers..

Solvent accelerated polymer diffusion in thin films (2005)
Journal Article
Thompson, R., McDonald, M., Lenthall, J., & Hutchings, L. (2005). Solvent accelerated polymer diffusion in thin films. Macromolecules, 38(10), 4339-4344. https://doi.org/10.1021/ma050317p

We have investigated the absorption of cyclohexane vapor into polystyrene films and the resulting polymer interdiffusion that is enabled by this process. The swelling of films due to solvent absorption was relatively insensitive to the film thickness... Read More about Solvent accelerated polymer diffusion in thin films.

Surface segregation and self-stratification in blends of spin-cast polyfluorene derivatives (2005)
Journal Article
Higgins, A., Martin, S., Thompson, R., Chappell, J., Voigt, M., Lidzey, D., …Geoghegan, M. (2005). Surface segregation and self-stratification in blends of spin-cast polyfluorene derivatives. Journal of Physics: Condensed Matter, 17(8), 1319-1328

We have used helium-3 nuclear reaction analysis to study the morphology of spin-cast blends of poly(9,9'-dioctylfluorene) (178) and poly(9,9'-dioctylfluorene-alt-benzothiadiazole) as a function of composition, casting solvent, and initial solvent con... Read More about Surface segregation and self-stratification in blends of spin-cast polyfluorene derivatives.