All Outputs (3)

Reaction of ruthenium(II) and osmium(II) hydrides with anhydrous HF (1997)
Journal Article
Coleman, K., Holloway, J., Hope, E., & Langer, J. (1997). Reaction of ruthenium(II) and osmium(II) hydrides with anhydrous HF. Journal of the Chemical Society. Dalton transactions (2001. Online), 4555-4559. https://doi.org/10.1039/a705582j

The reactions of anhydrous HF with the ruthenium(II) and osmium(II) hydride complexes [MH2(CO)(x)(PPh3)(y)] (M = Ru or Os; x = y = 2; x = 1, y = 3) have been studied. For [OC-6-13][MH2(CO)(2)(PPh3)(2)], elimination of dihydrogen affords the previousl... Read More about Reaction of ruthenium(II) and osmium(II) hydrides with anhydrous HF.

Air-stable ruthenium(II) and osmium(II) fluoride complexes. Crystal structures of [OC-6-13][MF2(CO)(2)(PR3)(2)] [M = Ru, PR3 = PEtPh2; M =Os, PR3 = PPh3 or P(C6H11)(3)] (1997)
Journal Article
Coleman, K., Fawcett, J., Holloway, J., Hope, E., & Russell, D. (1997). Air-stable ruthenium(II) and osmium(II) fluoride complexes. Crystal structures of [OC-6-13][MF2(CO)(2)(PR3)(2)] [M = Ru, PR3 = PEtPh2; M =Os, PR3 = PPh3 or P(C6H11)(3)]. Journal of the Chemical Society. Dalton transactions (2001. Online), 3557-3562. https://doi.org/10.1039/a702142i

The reaction of Lewis bases L with [{MF2(CO)(3)}(4)] (M=Ru or Os) in organic solvents provided a clean, high-yield, route to a series of air-and moisture-stable ruthenium(II) and osmium(II) fluoride co-ordination compounds of general formulae [MF2(CO... Read More about Air-stable ruthenium(II) and osmium(II) fluoride complexes. Crystal structures of [OC-6-13][MF2(CO)(2)(PR3)(2)] [M = Ru, PR3 = PEtPh2; M =Os, PR3 = PPh3 or P(C6H11)(3)].

Synthesis and characterisation of ruthenium carbonyl fluorides (1997)
Journal Article
Coleman, K., Holloway, J., & Hope, E. (1997). Synthesis and characterisation of ruthenium carbonyl fluorides. Journal of the Chemical Society. Dalton transactions (2001. Online), 1713-1717. https://doi.org/10.1039/a608357i

The oxidative fluorination of [Ru-3(CO)(12)] with XeF2 in anhydrous HF afforded, in solution, cis-[RuF2(CO)(4)] as the major product with [RuF(CO)(5)](+), [Ru2F4(CO)(7)], [{RuF(CO)(4)}(2)(mu-F)](+), mer- and fac-[RuF3(CO)(3)](-), [{RuF2(CO)(3)}(n)] a... Read More about Synthesis and characterisation of ruthenium carbonyl fluorides.