All Outputs (2)

Revisiting the Van Vleck second moment for characterizing molecular motion in organic solids (2023)
Journal Article
Sturniolo, S., Wickins, H. M., & Hodgkinson, P. (2023). Revisiting the Van Vleck second moment for characterizing molecular motion in organic solids. The Journal of Chemical Physics, 158(24), https://doi.org/10.1063/5.0151022

Van Vleck’s classic theory of the second moment of lineshapes in 1H nuclear magnetic resonance (NMR) is reworked in a form that allows the effect of rapid molecular motion on second moments to be calculated in a semi-analytical fashion. This is much... Read More about Revisiting the Van Vleck second moment for characterizing molecular motion in organic solids.

A new avenue to relaxor-like ferroelectric behaviour found by probing the structure and dynamics of [NH3NH2]Mg(HCO2)3 (2023)
Journal Article
Hitchings, T. J., Wickins, H. M., Peat, G. U. L., Hodgkinson, P., Srivastava, A. K., Lu, T., …Saines, P. J. (2023). A new avenue to relaxor-like ferroelectric behaviour found by probing the structure and dynamics of [NH3NH2]Mg(HCO2)3. Journal of Materials Chemistry C Materials for optical and electronic devices, 11(28), 9695-9706. https://doi.org/10.1039/d3tc00480e

The field of relaxor ferroelectrics has long been dominated by ceramic oxide materials exhibiting large polarisations with temperature and frequency dependence. Intriguingly, the dense metal–organic framework (MOF) [NH3NH2]Mg(HCO2)3 was reported as o... Read More about A new avenue to relaxor-like ferroelectric behaviour found by probing the structure and dynamics of [NH3NH2]Mg(HCO2)3.