All Outputs (8)

Cyclophane Molecules Exhibiting Thermally Activated Delayed Fluorescence: Linking Donor Units to Influence Molecular Conformation (2020)
Journal Article
Hempe, M., Harrison, A. K., Ward, J. S., Batsanov, A. S., Fox, M. A., Dias, F. B., & Bryce, M. R. (2021). Cyclophane Molecules Exhibiting Thermally Activated Delayed Fluorescence: Linking Donor Units to Influence Molecular Conformation. Journal of Organic Chemistry, 86(1), 429-445. https://doi.org/10.1021/acs.joc.0c02174

The synthetic methodology to covalently link donors to form cyclophane-based thermally activated delayed fluorescence (TADF) molecules is presented. These are the first reported examples of TADF cyclophanes with “electronically innocent” bridges betw... Read More about Cyclophane Molecules Exhibiting Thermally Activated Delayed Fluorescence: Linking Donor Units to Influence Molecular Conformation.

Resonance-enhanced charge delocalization in carbazole-oligoyne-oxadiazole conjugates (2020)
Journal Article
Zieleniewska, A., Zhao, X., Bauroth, S., Wang, C., Batsanov, A., Calderson, C., …Guldi, D. (2020). Resonance-enhanced charge delocalization in carbazole-oligoyne-oxadiazole conjugates. Journal of the American Chemical Society, 142(44), 18769-18781. https://doi.org/10.1021/jacs.0c04003

There are notably few literature reports of electron donor-acceptor oligoynes although they offer unique opportunities for studying charge transport through ‘all-carbon’ molecular bridges. In this context, the current study focuses on a series of car... Read More about Resonance-enhanced charge delocalization in carbazole-oligoyne-oxadiazole conjugates.

Isoniazid-Gentisic acid cocrystallization: Solubility, Stability, Dissolution rate, Antioxidant and Flowability Properties Studies (2020)
Journal Article
Mashhadi, S. M. A., Batsanov, A. S., Sajjad, S. A., Nazir, Y., Bhatti, M. H., & Yunus, U. (2021). Isoniazid-Gentisic acid cocrystallization: Solubility, Stability, Dissolution rate, Antioxidant and Flowability Properties Studies. Journal of Molecular Structure, 1226, Article 129388. https://doi.org/10.1016/j.molstruc.2020.129388

Isoniazid (INH) is a key antitubercular agent, which exhibits poor chemical stability in the solid state associated with the hydrazide group. Cocrystallization with Gentisic Acid having antioxidant activity, may produce solid forms with improved phar... Read More about Isoniazid-Gentisic acid cocrystallization: Solubility, Stability, Dissolution rate, Antioxidant and Flowability Properties Studies.

Carbazole isomers induce ultralong organic phosphorescence (2020)
Journal Article
Chen, C., Chi, Z., Chong, K. C., Batsanov, A. S., Yang, Z., Mao, Z., …Liu, B. (2021). Carbazole isomers induce ultralong organic phosphorescence. Nature Materials, 20(February 2021), 175-180. https://doi.org/10.1038/s41563-020-0797-2

Commercial carbazole has been widely used to synthesize organic functional materials that have led to recent breakthroughs in ultralong organic phosphorescence1, thermally activated delayed fluorescence2,3, organic luminescent radicals4 and organic s... Read More about Carbazole isomers induce ultralong organic phosphorescence.

Electronic conductance and thermopower of single-molecule junctions of oligo(phenyleneethynylene) derivatives (2020)
Journal Article
Dekkiche, H., Gemma, A., Tabatabaei, F., Batsanov, A. S., Niehaus, T., Gotsmann, B., & Bryce, M. R. (2020). Electronic conductance and thermopower of single-molecule junctions of oligo(phenyleneethynylene) derivatives. Nanoscale, 12(36), 18908-18917. https://doi.org/10.1039/d0nr04413j

We report the synthesis and the single-molecule transport properties of three new oligo(phenyleneethynylene) (OPE3) derivatives possessing terminal dihydrobenzo[b]thiophene (DHBT) anchoring groups and various core substituents (phenylene, 2,5-dimetho... Read More about Electronic conductance and thermopower of single-molecule junctions of oligo(phenyleneethynylene) derivatives.

Nitrogen Fixation and Biological Behavior of Nanodiamond Colloidal Solutions (2020)
Journal Article
Kurakov, A. V., Batsanov, A. S., Gavrilkin, S. M., & Batsanov, S. S. (2020). Nitrogen Fixation and Biological Behavior of Nanodiamond Colloidal Solutions. ChemPlusChem, 85(8), 1905-1911. https://doi.org/10.1002/cplu.202000437

Detonation‐produced nanodiamond, both as a powder (with adsorbed water) and especially when suspended in an aqueous colloid, can support the growth (both aerobic and anaerobic) of bacteria and fungi, which were isolated and identified by microbiologi... Read More about Nitrogen Fixation and Biological Behavior of Nanodiamond Colloidal Solutions.

Phosphorescent mono- and diiridium(III) complexes cyclometalated by fluorenyl- or phenyl-pyridino ligands with bulky substituents, as prospective OLED dopants (2020)
Journal Article
M'hamedi, A., & Batsanov, A. S. (2020). Phosphorescent mono- and diiridium(III) complexes cyclometalated by fluorenyl- or phenyl-pyridino ligands with bulky substituents, as prospective OLED dopants. Acta Crystallographica Section E: Crystallographic Communications, 76(3), 392-399. https://doi.org/10.1107/s2056989020001784

The crystal structures of tris­[9,9-dihexyl-2-(5-meth­oxy­pyridin-2-yl-κN)-9H-fluoren-3-yl-κC3]iridium pentane monosolvate, [Ir(C31H38NO)3]·C5H12, (I), di-μ2-chlorido-bis­{bis­[2-(5-fluoro­pyridin-2-yl)-9,9-dihexyl-9H-fluoren-3-yl]iridium} pentane 0.... Read More about Phosphorescent mono- and diiridium(III) complexes cyclometalated by fluorenyl- or phenyl-pyridino ligands with bulky substituents, as prospective OLED dopants.

Unusual dual-emissive heteroleptic iridium complexes incorporating TADF cyclometalating ligands (2020)
Journal Article
Benjamin, H., Zheng, Y., Kozhevnikov, V. N., Siddle, J. S., O'Driscoll, L. J., Fox, M. A., …Bryce, M. R. (2020). Unusual dual-emissive heteroleptic iridium complexes incorporating TADF cyclometalating ligands. Dalton Transactions, 49(7), 2190-2208. https://doi.org/10.1039/c9dt04672k

Five new neutral heteroleptic iridium(III) complexes IrL2(pic) (2–6) based on the archetypical blue emitter FIrpic have been synthesised. The cyclometallating ligands L are derived from 2-(2,6-F2-3-pyridyl)-4-mesitylpyridine (7), 2-(3-cyano-2,6-F2-ph... Read More about Unusual dual-emissive heteroleptic iridium complexes incorporating TADF cyclometalating ligands.