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Sterically-controlled regioselective para-substitutions of aniline

Dyer, P.W.; Fawcett, J.; Griffith, G.A.; Hanton, M.J.; Olivier, C.; Patterson, A.R.; Suhard, S.


J. Fawcett

G.A. Griffith

M.J. Hanton

C. Olivier

A.R. Patterson

S. Suhard


Introduction of sterically demanding 1-isopropyl-2-methyl-propyl or triisopropylsilyl groups at the nitrogen of aniline allows high-yielding regioselective para-substitution to be achieved using a lithiation/substitution sequence.


Dyer, P., Fawcett, J., Griffith, G., Hanton, M., Olivier, C., Patterson, A., & Suhard, S. (2005). Sterically-controlled regioselective para-substitutions of aniline. Chemical Communications, 3835-3837.

Journal Article Type Article
Publication Date Jun 1, 2005
Deposit Date May 10, 2007
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Issue 30
Pages 3835-3837