Hosomi-Sakurai reactions of silacyclic allyl silanes

Sellars, J.D.; Steel, P.G.; Turner, M.J.

Abstract

Substituted silacyclohexenes, generated through silene–diene [4 + 2] cycloaddition reactions, undergo Lewis acid promoted Sakurai type reactions with acetals to afford, following oxidation of the resultant fluorosilane, 1,4-diols with four contiguous chiral centres.

Citation

Sellars, J., Steel, P., & Turner, M. (2006). Hosomi-Sakurai reactions of silacyclic allyl silanes. Chemical Communications, 2006(22), 2385-2387. https://doi.org/10.1039/b602642g

• Journal Article Type: Article
• Acceptance Date: Apr 11, 2006
• Online Publication Date: May 2, 2006
• Publication Date: 2006
• Deposit Date: May 4, 2007
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 2006
• Issue: 22
• Pages: 2385-2387
• DOI: https://doi.org/10.1039/b602642g
• Public URL: https://durham-repository.worktribe.com/output/1542602