Hosomi-Sakurai Reactions of Silacyclohexenes

Hughes, N.J.; Pullin, R.D.C.; Sanganee, M.J.; Sellars, J.D.; Steel, P.G.; Turner, M.J.

Abstract

Silacyclic allyl silanes, derived from silene–diene Diels–Alder reactions, combine with acetals in the presence of Lewis acids to afford, following oxidation of the intermediate fluorosilane, either butane-1,4-diols or tetrahydronaphthalenes containing four contiguous chiral centres with moderate to good diastereoselectivity.

Citation

Hughes, N., Pullin, R., Sanganee, M., Sellars, J., Steel, P., & Turner, M. (2007). Hosomi-Sakurai Reactions of Silacyclohexenes. Organic and Biomolecular Chemistry, 5(17), 2841-2848. https://doi.org/10.1039/b709318g

• Journal Article Type: Article
• Publication Date: Jul 1, 2007
• Deposit Date: Jan 18, 2008
• Journal: Organic and Biomolecular Chemistry
• Print ISSN: 1477-0520
• Electronic ISSN: 1477-0539
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 5
• Issue: 17
• Pages: 2841-2848
• DOI: https://doi.org/10.1039/b709318g
• Public URL: https://durham-repository.worktribe.com/output/1535507