Photodissociation of oriented HXeI molecules generated from HI-Xe_n clusters

Nahler, N.H.; Baumfalk, R.; Buck, U.; Bihary, Z.; Gerber, R.B.; Friedrich, B.

Abstract

We report the production in the gas phase of ionically bound HXeI molecules. The molecules are generated by the photodissociation of HI molecules in large Xen clusters and are identified from the asymmetry of the detected H atom fragments arising from the dissociation of oriented HXeI. The orientation, resulting from a synergistic action of a pulsed laser field with a weak electrostatic field, is quite pronounced, due to a large ratio of the polarizability anisotropy to the rotational constant of HXeI.

Citation

Nahler, N., Baumfalk, R., Buck, U., Bihary, Z., Gerber, R., & Friedrich, B. (2003). Photodissociation of oriented HXeI molecules generated from HI-Xen clusters. The Journal of Chemical Physics, 119(1), 224-231. https://doi.org/10.1063/1.1577311

• Journal Article Type: Article
• Acceptance Date: Apr 3, 2003
• Online Publication Date: Jul 1, 2003
• Publication Date: Jul 1, 2003
• Deposit Date: Jan 18, 2008
• Journal: Journal of Chemical Physics
• Print ISSN: 0021-9606
• Electronic ISSN: 1089-7690
• Publisher: American Institute of Physics
• Peer Reviewed: Peer Reviewed
• Volume: 119
• Issue: 1
• Pages: 224-231
• DOI: https://doi.org/10.1063/1.1577311