Synthesis and molecular structure of a perfluorinated pyridyl carbanion

Colgin, N.; Tatum, N.J.; Pohl, E.; Cobb, S.L.; Sandford, G.

Abstract

Reaction of pentafluoropyridine with sodium nitromethanide allowed the isolation and characterisation of the first perfluorinated pyridyl carbanion system, sodium nitrobis(perfluoropyridin-4-yl)methanide, by X-ray crystallography.

Citation

Colgin, N., Tatum, N., Pohl, E., Cobb, S., & Sandford, G. (2012). Synthesis and molecular structure of a perfluorinated pyridyl carbanion. Journal of Fluorine Chemistry, 133, 33-37. https://doi.org/10.1016/j.jfluchem.2011.09.013

• Journal Article Type: Article
• Publication Date: 2012-01
• Deposit Date: Feb 6, 2012
• Journal: Journal of Fluorine Chemistry
• Print ISSN: 0022-1139
• Publisher: Elsevier
• Peer Reviewed: Peer Reviewed
• Volume: 133
• Pages: 33-37
• DOI: https://doi.org/10.1016/j.jfluchem.2011.09.013