Crystallization of deformable spherical colloids.

Batista, V.M.O.; Miller, M.A.

Abstract

We introduce and characterize a first-order model for a generic class of colloidal particles that have a preferred spherical shape but can undergo deformations while always maintaining hard-body interactions. The model consists of hard spheres that can continuously change shape at fixed volume into prolate or oblate ellipsoids of revolution, subject to an energetic penalty. The severity of this penalty is specified by a single parameter that determines the flexibility of the particles. The deformable hard spheres crystallize at higher packing fractions than rigid hard spheres, have a narrower solid-fluid coexistence region and can reach high densities by a second transition to an orientationally ordered crystal.

Citation

Batista, V., & Miller, M. (2010). Crystallization of deformable spherical colloids. Physical Review Letters, 105(8), Article 088305. https://doi.org/10.1103/physrevlett.105.088305

• Journal Article Type: Article
• Publication Date: 2010-08
• Deposit Date: Apr 11, 2013
• Journal: Physical Review Letters
• Print ISSN: 0031-9007
• Electronic ISSN: 1079-7114
• Publisher: American Physical Society
• Peer Reviewed: Peer Reviewed
• Volume: 105
• Issue: 8
• Article Number: 088305
• DOI: https://doi.org/10.1103/physrevlett.105.088305
• Public URL: https://durham-repository.worktribe.com/output/1487558