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Phosphine-alkene ligand-mediated alkyl-alkyl and alkyl-halide elimination processes from palladium(II)

Tuxworth, Luke; Baiget, Lise; Phanopoulos, Andreas; Metters, Owen J.; Batsanov, Andrei S.; Fox, Mark A.; Howard, Judith A.K.; Dyer, Philip W.

Phosphine-alkene ligand-mediated alkyl-alkyl and alkyl-halide elimination processes from palladium(II) Thumbnail


Authors

Luke Tuxworth

Lise Baiget

Andreas Phanopoulos

Owen J. Metters

Andrei S. Batsanov

Judith A.K. Howard



Abstract

N-Diphenylphosphino-7-aza-benzobicyclo[2.2.1]hept-2-ene (2) behaves as a chelating phosphine–alkene ligand for Pd0 and PdII, promoting direct alkyl–alkyl and indirect alkyl–halide reductive elimination reactions due to the stabilisation of the resulting bis(phosphine–alkene)Pd0 complex.

Citation

Tuxworth, L., Baiget, L., Phanopoulos, A., Metters, O. J., Batsanov, A. S., Fox, M. A., …Dyer, P. W. (2012). Phosphine-alkene ligand-mediated alkyl-alkyl and alkyl-halide elimination processes from palladium(II). Chemical Communications, 48(84), 10413-10415. https://doi.org/10.1039/c2cc35623f

Journal Article Type Article
Publication Date Sep 26, 2012
Deposit Date May 2, 2013
Publicly Available Date Jul 18, 2014
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 48
Issue 84
Pages 10413-10415
DOI https://doi.org/10.1039/c2cc35623f
Public URL https://durham-repository.worktribe.com/output/1477460

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