Identifying champion nanostructures for solar water-splitting

Warren, S.C.; Voïtchovsky, K.; Dotan, H.; Leroy, C.M.; Cornuz, M.; Stellacci, F.; Hébert, C.; Rothschild, A.; Grätzel, M.

Abstract

Charge transport in nanoparticle-based materials underlies many emerging energy-conversion technologies, yet assessing the impact of nanometre-scale structure on charge transport across micrometre-scale distances remains a challenge. Here we develop an approach for correlating the spatial distribution of crystalline and current-carrying domains in entire nanoparticle aggregates. We apply this approach to nanoparticle-based α-Fe2O3 electrodes that are of interest in solar-to-hydrogen energy conversion. In correlating structure and charge transport with nanometre resolution across micrometre-scale distances, we have identified the existence of champion nanoparticle aggregates that are most responsible for the high photoelectrochemical activity of the present electrodes. Indeed, when electrodes are fabricated with a high proportion of these champion nanostructures, the electrodes achieve the highest photocurrent of any metal oxide photoanode for photoelectrochemical water-splitting under 100 mW cm−2 air mass 1.5 global sunlight.

Citation

Warren, S., Voïtchovsky, K., Dotan, H., Leroy, C., Cornuz, M., Stellacci, F., …Grätzel, M. (2013). Identifying champion nanostructures for solar water-splitting. Nature Materials, 12(9), 842-849. https://doi.org/10.1038/nmat3684

• Journal Article Type: Article
• Publication Date: Sep 1, 2013
• Deposit Date: Sep 26, 2013
• Publicly Available Date: Dec 11, 2014
• Journal: Nature Materials
• Print ISSN: 1476-1122
• Electronic ISSN: 1476-4660
• Publisher: Nature Research
• Peer Reviewed: Peer Reviewed
• Volume: 12
• Issue: 9
• Pages: 842-849
• DOI: https://doi.org/10.1038/nmat3684
• Public URL: https://durham-repository.worktribe.com/output/1469127