Optimizing the high-field relaxivity by self-assembling of macrocyclic Gd(III) complexes

Lawson, D.; Barge, A.; Terreno, E.; Parker, D.; Aime, S.; Botta, M.

Abstract

Using recognition moieties that bind to the inner co-ordination sphere of a monomeric DO3A-type di-aqua complex, dimeric poly(aminocarboxylate) gadolinium(III) compounds can be formed with greatly enhanced relaxivities, arising from optimized contributions of inner- and second spheres of hydration.

Citation

Lawson, D., Barge, A., Terreno, E., Parker, D., Aime, S., & Botta, M. (2015). Optimizing the high-field relaxivity by self-assembling of macrocyclic Gd(III) complexes. Dalton Transactions, 44(11), 4910-4917. https://doi.org/10.1039/c4dt02971b

• Journal Article Type: Article
• Publication Date: Mar 21, 2015
• Deposit Date: Nov 14, 2014
• Publicly Available Date: Nov 20, 2014
• Journal: Dalton Transactions
• Print ISSN: 1477-9226
• Electronic ISSN: 1477-9234
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 44
• Issue: 11
• Pages: 4910-4917
• DOI: https://doi.org/10.1039/c4dt02971b
• Public URL: https://durham-repository.worktribe.com/output/1420095