Highly Linearized Twisted Iridium(III) Complexes

Davidson, Ross; Hsu, Yu-Ting; Griffiths, Gareth C.; Li, Chenfei; Yufit, Dmitry; Pal, Robert; Beeby, Andrew

doi:10.1021/acs.inorgchem.8b02818

Highly Linearized Twisted Iridium(III) Complexes

Davidson, Ross; Hsu, Yu-Ting; Griffiths, Gareth C.; Li, Chenfei; Yufit, Dmitry; Pal, Robert; Beeby, Andrew

Authors

Dr Ross Davidson ross.davidson@durham.ac.uk
Academic Visitor

Yu-Ting Hsu

Gareth C. Griffiths

Chenfei Li

Dr Dmitry Yufit d.s.yufit@durham.ac.uk
Academic Visitor

Professor Robert Pal robert.pal@durham.ac.uk
Professor

Professor Andrew Beeby andrew.beeby@durham.ac.uk
Professor

Abstract

Sonogashira coupling with alkyne iridium(phenylpyridine)2(acetylacetone) synthons is used to produce highly linearized twisted iridium(III) complexes with lengths of up to 5 nm. These complexes were mechanically aligned in a polymer matrix, showing an improved contrast ratio with increased length.

Citation

Davidson, R., Hsu, Y.-T., Griffiths, G. C., Li, C., Yufit, D., Pal, R., & Beeby, A. (2018). Highly Linearized Twisted Iridium(III) Complexes. Inorganic Chemistry, 57(22), 14450-14462. https://doi.org/10.1021/acs.inorgchem.8b02818

Journal Article Type	Article
Acceptance Date	Oct 25, 2018
Online Publication Date	Nov 1, 2018
Publication Date	Nov 19, 2018
Deposit Date	Nov 2, 2018
Publicly Available Date	Nov 1, 2019
Journal	Inorganic Chemistry
Print ISSN	0020-1669
Electronic ISSN	1520-510X
Publisher	American Chemical Society
Peer Reviewed	Peer Reviewed
Volume	57
Issue	22
Pages	14450-14462
DOI	https://doi.org/10.1021/acs.inorgchem.8b02818
Public URL	https://durham-repository.worktribe.com/output/1314236

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Copyright Statement
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.8b02818.