Spectroscopic characterisation of radical polyinterhalogen molecules

Gregory, Joe; Verlet, Jan R.R.; Bull, James N.

Abstract

Spectroscopic characterisations of the radical polyinterhalogen molecules IF2 and I2F are reported using anion photoelectron spectroscopy. The corresponding parent anions, IF2− and I2F−, are common products formed in hard Ar–CF3I plasmas and are relevant in the semiconductor manufacture industry. The I2F− species, which is present as the [I–I–F]− isomer, is a “non-classical” polyinterhalogen.

Citation

Gregory, J., Verlet, J. R., & Bull, J. N. (2020). Spectroscopic characterisation of radical polyinterhalogen molecules. Physical Chemistry Chemical Physics, 22(16), 8284-8288. https://doi.org/10.1039/d0cp01311k

• Journal Article Type: Article
• Acceptance Date: Apr 3, 2020
• Online Publication Date: Apr 3, 2020
• Publication Date: Apr 28, 2020
• Deposit Date: May 13, 2020
• Publicly Available Date: Apr 3, 2021
• Journal: Physical Chemistry Chemical Physics
• Print ISSN: 1463-9076
• Electronic ISSN: 1463-9084
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 22
• Issue: 16
• Pages: 8284-8288
• DOI: https://doi.org/10.1039/d0cp01311k
• Public URL: https://durham-repository.worktribe.com/output/1302097