Simon Paredis
Balanced Energy Gaps as a Key Design Rule for Solution‐Phase Organic Room Temperature Phosphorescence
Paredis, Simon; Cardeynaels, Tom; Kuila, Suman; Deckers, Jasper; Van Landeghem, Melissa; Vandewal, Koen; Danos, Andrew; Monkman, Andrew P.; Champagne, Benoît; Maes, Wouter
Authors
Tom Cardeynaels
Suman Kuila suman.kuila@durham.ac.uk
Post Doctoral Research Associate
Jasper Deckers
Melissa Van Landeghem
Koen Vandewal
Dr Andrew Danos andrew.danos@durham.ac.uk
Senior Experimental Officer
Professor Andrew Monkman a.p.monkman@durham.ac.uk
Professor
Benoît Champagne
Wouter Maes
Abstract
Metal-free organic emitters that display solution-phase room temperature phosphorescence (sRTP) remain exceedingly rare. Here, we investigate the structural and photophysical properties that support sRTP by comparing a recently reported sRTP compound (BTaz-Th-PXZ) to two novel analogous materials, replacing the donor group by either acridine or phenothiazine. The emissive triplet excited state remains fixed in all three cases, while the emissive charge-transfer singlet states (and the calculated paired charge-transfer T2 state) vary with the donor unit. While all three materials show dominant RTP in film, in solution different singlet-triplet and triplet-triplet energy gaps give rise to triplet-triplet annihilation followed by weak sRTP for the new compounds, compared to dominant sRTP throughout for the original PXZ material. Engineering both the sRTP state and higher charge-transfer states therefore emerges as a crucial element in designing emitters capable of sRTP.
Citation
Paredis, S., Cardeynaels, T., Kuila, S., Deckers, J., Van Landeghem, M., Vandewal, K., …Maes, W. (2023). Balanced Energy Gaps as a Key Design Rule for Solution‐Phase Organic Room Temperature Phosphorescence. Chemistry - A European Journal, https://doi.org/10.1002/chem.202301369
Journal Article Type | Article |
---|---|
Acceptance Date | May 8, 2023 |
Online Publication Date | May 8, 2023 |
Publication Date | 2023 |
Deposit Date | May 9, 2023 |
Publicly Available Date | May 9, 2024 |
Journal | Chemistry – A European Journal |
Print ISSN | 0947-6539 |
Electronic ISSN | 1521-3765 |
Publisher | Wiley |
Peer Reviewed | Peer Reviewed |
DOI | https://doi.org/10.1002/chem.202301369 |
Public URL | https://durham-repository.worktribe.com/output/1175576 |
Files
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