Allocation of Ambipolar Charges on an Organic Diradical with a Vinylene–Phenylenediyne Bridge (2021)
Journal Article
Mayorga-Burrezo, P., Bejarano, F., Calbo, J., Zhao, X., De Sousa, J. A., Lloveras, V., …Crivillers, N. (2021). Allocation of Ambipolar Charges on an Organic Diradical with a Vinylene–Phenylenediyne Bridge. Journal of Physical Chemistry Letters, 12(26), 6159-6164. https://doi.org/10.1021/acs.jpclett.1c01565

Two redox and magnetically active perchlorotriphenylmethyl (•PTM) radical units have been connected as end-capping groups to a bis(phenylene)diyne chain through vinylene linkers. Negative and positive charged species have been generated, and the infl... Read More about Allocation of Ambipolar Charges on an Organic Diradical with a Vinylene–Phenylenediyne Bridge.

Resonance-enhanced charge delocalization in carbazole-oligoyne-oxadiazole conjugates (2020)
Journal Article
Zieleniewska, A., Zhao, X., Bauroth, S., Wang, C., Batsanov, A., Calderson, C., …Guldi, D. (2020). Resonance-enhanced charge delocalization in carbazole-oligoyne-oxadiazole conjugates. Journal of the American Chemical Society, 142(44), 18769-18781. https://doi.org/10.1021/jacs.0c04003

There are notably few literature reports of electron donor-acceptor oligoynes although they offer unique opportunities for studying charge transport through ‘all-carbon’ molecular bridges. In this context, the current study focuses on a series of car... Read More about Resonance-enhanced charge delocalization in carbazole-oligoyne-oxadiazole conjugates.