Skip to main content

Research Repository

Advanced Search

The first genuine observation of fluorescent mononuclear phthalocyanine aggregates (2002)
Journal Article
Farren, C., FitzGerald, S., Beeby, A., & Bryce, M. (2002). The first genuine observation of fluorescent mononuclear phthalocyanine aggregates. Chemical Communications, 572-573

An initial photophysical study of a tetra-solketal-substituted zinc phthalocyanine is reported; at low temperature this compound exhibits very strong aggregation, and a new red shifted emission peak is observed, lambda(max) approximate to750 nm, attr... Read More about The first genuine observation of fluorescent mononuclear phthalocyanine aggregates.

Synthesis of novel phthalocyanine-tetrathiafulvalene hybrids; Intramolecular fluorescence quenching related to molecular geometry (2002)
Journal Article
Farren, C., Christensen, C., FitzGerald, S., Bryce, M., & Beeby, A. (2002). Synthesis of novel phthalocyanine-tetrathiafulvalene hybrids; Intramolecular fluorescence quenching related to molecular geometry. Journal of Organic Chemistry, 67(26), 9130-9139

A number of silicon phthalocyanine bis-esters have been synthesized and characterized, with axial ligands containing one or more tetrathiafulvalene groups. Variations in the substitution positions around a central aromatic "hinge" within the ligands... Read More about Synthesis of novel phthalocyanine-tetrathiafulvalene hybrids; Intramolecular fluorescence quenching related to molecular geometry.

Structural, luminescence, and NMR studies of the reversible binding of acetate, lactate, citrate, and selected amino acids to chiral diaqua ytterbium, gadolinium, and europium complexes (2002)
Journal Article
Dickins, R., Aime, S., Batsanov, A., Beeby, A., Botta, M., Bruce, J., …Puschmann, H. (2002). Structural, luminescence, and NMR studies of the reversible binding of acetate, lactate, citrate, and selected amino acids to chiral diaqua ytterbium, gadolinium, and europium complexes. Journal of the American Chemical Society, 124(43), 12697-12705. https://doi.org/10.1021/ja020836x

The nature of the ternary complexes formed in aqueous media at ambient pH on reversible binding of acetate, lactate, citrate, and selected amino acids and peptides to chiral diaqua europium, gadolinium, or ytterbium cationic complexes has been examin... Read More about Structural, luminescence, and NMR studies of the reversible binding of acetate, lactate, citrate, and selected amino acids to chiral diaqua ytterbium, gadolinium, and europium complexes.

Fluorescent phthalocyanine dimers - a steady state and flash photolysis study (2002)
Journal Article
FitzGerald, S., Farren, C., Stanley, C., Beeby, A., & Bryce, M. (2002). Fluorescent phthalocyanine dimers - a steady state and flash photolysis study. Photochemical & Photobiological Sciences, 1(8), 581-587

Steady state and time resolved studies of a tetrakis[(+/-)-2,2-dimethyl-1,3-dioxan-4-ylmethanol] (solketal) substituted zinc phthalocyanine (1) and its derivatives (4a-c) are reported. These compounds form novel fluorescent dimers (or higher order ag... Read More about Fluorescent phthalocyanine dimers - a steady state and flash photolysis study.

A re-evaluation of the photophysical properties of 1,4-bis(phenylethynyl)benzene: A model for poly(phenyleneethynylene) (2002)
Journal Article
Beeby, A., Findlay, K., Low, P., & Marder, T. (2002). A re-evaluation of the photophysical properties of 1,4-bis(phenylethynyl)benzene: A model for poly(phenyleneethynylene). Journal of the American Chemical Society, 124(28), 8280-8284. https://doi.org/10.1021/ja025568h

Photophysical measurements, recorded in aerated cyclohexane at 283 K, indicate that 1,4-bis-(phenylethynyl) benzene behaves in a conventional manner, undergoing emission from the lowest vibrational level of the first excited singlet state; there is n... Read More about A re-evaluation of the photophysical properties of 1,4-bis(phenylethynyl)benzene: A model for poly(phenyleneethynylene).

Synthesis, structure and optical characterisation of silicon phthalocyanine bis-esters (2002)
Journal Article
Farren, C., FitzGerald, S., Bryce, M., Beeby, A., & Batsanov, A. (2002). Synthesis, structure and optical characterisation of silicon phthalocyanine bis-esters. Journal of the Chemical Society-Perkin Transactions 2, 59-66

A range of axially substituted silicon phthalocyanines has been synthesised using various carboxylates as the ligands. 4-tert-Butylbenzoic acid gives rigid, orthogonal axial substituents, whilst a thiophene-containing bis-acetate was conformationally... Read More about Synthesis, structure and optical characterisation of silicon phthalocyanine bis-esters.