Rebecca Salthouse's Outputs (7)

Dinuclear platinum( ii ) complexes featuring rigidly linked Pt( NCN )X units: the effect of X = SCN − in favouring low-energy, excimer-like luminescence (2024)
Journal Article
Salthouse, R. J., Dikova, Y. M., Etherington, M. K., & Williams, J. A. G. (2024). Dinuclear platinum( ii ) complexes featuring rigidly linked Pt( NCN )X units: the effect of X = SCN − in favouring low-energy, excimer-like luminescence. New Journal of Chemistry, 48(44), 18865-18872. https://doi.org/10.1039/d4nj03357d

Interfacial intermolecular interactions between phosphorescent, square-planar, cyclometallated platinum(ii) complexes may lead to the formation of bimolecular excited states that emit at lower energy than the isolated complexes in dilute solution. We... Read More about Dinuclear platinum( ii ) complexes featuring rigidly linked Pt( NCN )X units: the effect of X = SCN − in favouring low-energy, excimer-like luminescence.

The Conductance and Thermopower Behavior of Pendent Trans -Coordinated Palladium(II) Complexes in Single-Molecule Junctions (2024)
Journal Article
Bastante, P., Davidson, R. J., Al Malki, W., Salthouse, R. J., Cea, P., Martin, S., Batsanov, A. S., Lambert, C. J., Bryce, M. R., & Agrait, N. (2024). The Conductance and Thermopower Behavior of Pendent Trans -Coordinated Palladium(II) Complexes in Single-Molecule Junctions. ACS Omega, 9(36), 38303-38312. https://doi.org/10.1021/acsomega.4c06475

The present work provides insight into the effect of connectivity within isomeric 1,2-bis­(2-pyridylethynyl)­benzene (bpb) palladium complexes on their electron transmission properties within gold|single-molecule|gold junctions. The ligands 2,2′-((4,... Read More about The Conductance and Thermopower Behavior of Pendent Trans -Coordinated Palladium(II) Complexes in Single-Molecule Junctions.

Isomeric modulation of thermally activated delayed fluorescence in dibenzo[ a, c ]phenazine-based (deep) red emitters (2024)
Journal Article
Brebels, S., Cardeynaels, T., Jackers, L., Kuila, S., Penxten, H., Salthouse, R. J., Danos, A., Monkman, A. P., Champagne, B. R., & Maes, W. (2024). Isomeric modulation of thermally activated delayed fluorescence in dibenzo[ a, c ]phenazine-based (deep) red emitters. Journal of Materials Chemistry C Materials for optical and electronic devices, 12(25), 9255-9265. https://doi.org/10.1039/d4tc01214c

A series of four emissive regio-isomers are synthesized based on the dibenzo[a, c]phenazine-11,12-dicarbonitrile (DBPzCN) acceptor scaffold and a triphenylamine (TPA) donor. Density functional theory is utilized to compare the relative differences in... Read More about Isomeric modulation of thermally activated delayed fluorescence in dibenzo[ a, c ]phenazine-based (deep) red emitters.

Exploring the Impact of the HOMO–LUMO Gap on Molecular Thermoelectric Properties: A Comparative Study of Conjugated Aromatic, Quinoidal, and Donor–Acceptor Core Systems (2024)
Journal Article
Blankevoort, N., Bastante, P., Davidson, R. J., Salthouse, R. J., Daaoub, A. H. S., Cea, P., …Sadeghi, H. (2024). Exploring the Impact of the HOMO–LUMO Gap on Molecular Thermoelectric Properties: A Comparative Study of Conjugated Aromatic, Quinoidal, and Donor–Acceptor Core Systems. ACS Omega, 9(7), 8471-8477. https://doi.org/10.1021/acsomega.3c09760

Thermoelectric materials have garnered significant interest for their potential to efficiently convert waste heat into electrical energy at room temperature without moving parts or harmful emissions. This study investigated the impact of the HOMO–LUM... Read More about Exploring the Impact of the HOMO–LUMO Gap on Molecular Thermoelectric Properties: A Comparative Study of Conjugated Aromatic, Quinoidal, and Donor–Acceptor Core Systems.

Rigidly linked dinuclear platinum( ii ) complexes showing intense, excimer-like, near-infrared luminescence (2023)
Journal Article
Pander, P., Walden, M. T., Salthouse, R. J., Sil, A., Yufit, D. S., Dias, F. B., & Williams, J. A. G. (2023). Rigidly linked dinuclear platinum( ii ) complexes showing intense, excimer-like, near-infrared luminescence. Journal of Materials Chemistry C Materials for optical and electronic devices, 11(43), 15335-15346. https://doi.org/10.1039/d3tc03432a

Many luminescent platinum(ii) complexes undergo face-to-face interactions between neighbouring molecules, leading to bimolecular excited states that may emit at lower energy (dimers and/or excimers). Detailed photophysical studies are reported on din... Read More about Rigidly linked dinuclear platinum( ii ) complexes showing intense, excimer-like, near-infrared luminescence.

Platinum(II) Complexes of Nonsymmetrical NCN-Coordinating Ligands: Unimolecular and Excimeric Luminescence Properties and Comparison with Symmetrical Analogues (2023)
Journal Article
Salthouse, R. J., Sil, A., Gildea, L. F., Yufit, D. S., & Williams, J. A. G. (2023). Platinum(II) Complexes of Nonsymmetrical NCN-Coordinating Ligands: Unimolecular and Excimeric Luminescence Properties and Comparison with Symmetrical Analogues. Inorganic Chemistry, 62(31), 12356-12371. https://doi.org/10.1021/acs.inorgchem.3c01439

A series of seven new platinum(II) complexes PtLnCl have been prepared, where Ln is an NCN-coordinating ligand comprising a benzene ring 1,3-disubstituted with two different azaheterocycles. In PtL1–5Cl, one heterocycle is a simple pyridine ring, whi... Read More about Platinum(II) Complexes of Nonsymmetrical NCN-Coordinating Ligands: Unimolecular and Excimeric Luminescence Properties and Comparison with Symmetrical Analogues.

Electronic Conductance and Thermopower of Cross-Conjugated and Skipped-Conjugated Molecules in Single-Molecule Junctions (2023)
Journal Article
Salthouse, R. J., Hurtado-Gallego, J., Grace, I. M., Davidson, R., Alshammari, O., Agraït, N., …Bryce, M. R. (2023). Electronic Conductance and Thermopower of Cross-Conjugated and Skipped-Conjugated Molecules in Single-Molecule Junctions. Journal of Physical Chemistry C, 127(28), 13751-13758. https://doi.org/10.1021/acs.jpcc.3c00742

We report a combined experimental and theoretical study of a series of thiomethyl (SMe) anchored cross-conjugated molecules featuring an acyclic central bridging ketone and their analogous skipped-conjugated alcohol derivatives. Studies of these mole... Read More about Electronic Conductance and Thermopower of Cross-Conjugated and Skipped-Conjugated Molecules in Single-Molecule Junctions.