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Electrochemically grafted single molecule junctions exploiting a chemical protection strategy (2016)
Journal Article
Liang, J., Smith, R. E., Vezzoli, A., Xie, L., Milan, D. C., Davidson, R., Beeby, A., Low, P. J., Higgins, S. J., Mao, B., & Nichols, R. J. (2016). Electrochemically grafted single molecule junctions exploiting a chemical protection strategy. Electrochimica Acta, 220, 436-443. https://doi.org/10.1016/j.electacta.2016.10.095

Diazonium grafted oligo(phenylene ethynylene) (OPE) monolayers suitable for single molecule conductance studies have been prepared. The surface-bound OPE is prepared from the amino tolan, 4-(2-(4-(2-(triisopropylsilyl)ethynyl)phenyl)ethynyl)benzamine... Read More about Electrochemically grafted single molecule junctions exploiting a chemical protection strategy.

Guidelines for measurement of luminescence spectra and quantum yields of inorganic and organometallic compounds in solution and solid state (IUPAC Technical Report) (2016)
Journal Article
Ishida, H., Bünzli, J., & Beeby, A. (2016). Guidelines for measurement of luminescence spectra and quantum yields of inorganic and organometallic compounds in solution and solid state (IUPAC Technical Report). Pure and Applied Chemistry, 88(7), 701-711. https://doi.org/10.1515/pac-2014-0706

Guidelines for measuring the luminescence of inorganic compounds, metal complexes, and organometallic compounds are described. Common textbooks and manuals describing luminescence measurements are usually targeted for organic compounds, and are not a... Read More about Guidelines for measurement of luminescence spectra and quantum yields of inorganic and organometallic compounds in solution and solid state (IUPAC Technical Report).

Illuminators' Pigments in Lancastrian England (2016)
Journal Article
Beeby, A., Gameson, R., & Nicholson, C. (2016). Illuminators' Pigments in Lancastrian England. Manuscripta, 60(2), 143-164. https://doi.org/10.1484/j.mss.5.111916

The pigments used in four high-status, datable, late medieval English manuscripts are identified by scientific methods. The palette and painting techniques of the illuminators responsible are studied individually then comparatively.

The use of organolithium reagents for the synthesis of 4-aryl-2-phenylpyridines and their corresponding iridium(III)complexes (2016)
Journal Article
Davidson, R., Hsu, Y., Batchelor, T., Yufit, D., & Beeby, A. (2016). The use of organolithium reagents for the synthesis of 4-aryl-2-phenylpyridines and their corresponding iridium(III)complexes. Dalton Transactions, 45(28), 11496-11507. https://doi.org/10.1039/c6dt01461e

A versatile palladium-free route for the synthesis of 4-aryl-substituted phenylpyridines (ppy), starting from tert-butyl 4-oxopiperidine-1-carboxylate, is reported. Reaction with an aryllithium, followed by trifluoroacetic acid dehydration/deprotecti... Read More about The use of organolithium reagents for the synthesis of 4-aryl-2-phenylpyridines and their corresponding iridium(III)complexes.

Single-Molecule Conductance of Viologen–Cucurbit[8]uril Host–Guest Complexes (2016)
Journal Article
Zhang, W., Gan, S., Vezzoli, A., Davidson, R., Milan, D., Luzyanin, K., …Niu, L. (2016). Single-Molecule Conductance of Viologen–Cucurbit[8]uril Host–Guest Complexes. ACS Nano, 10(5), 5212-5220. https://doi.org/10.1021/acsnano.6b00786

The local molecular environment is a critical factor which should be taken into account when measuring single-molecule electrical properties in condensed media or in the design of future molecular electronic or single molecule sensing devices. Supram... Read More about Single-Molecule Conductance of Viologen–Cucurbit[8]uril Host–Guest Complexes.

Anisotropic lanthanide-based nano-clusters for imaging applications (2016)
Journal Article
Yang, X., Wang, S., King, T. L., Kerr, C. J., Blanchet, C., Svergun, D., …Huang, S. (2016). Anisotropic lanthanide-based nano-clusters for imaging applications. Faraday Discussions, 191, 465-479. https://doi.org/10.1039/c6fd00018e

We have developed a new class of lanthanide nano-clusters that self-assemble using flexible Schiff base ligands. Cd–Ln and Ni–Ln clusters, [Ln8Cd24(L1)12(OAc)39Cl7(OH)2] (Ln = Nd, Eu), [Eu8Cd24(L1)12(OAc)44], [Ln8Cd24(L2)12(OAc)44] (Ln = Nd, Yb, Sm)... Read More about Anisotropic lanthanide-based nano-clusters for imaging applications.