Calcite Dissolution-Reprecipitation Reactions Are a Key Control on the Sr/Ca, Mg/Ca and δ88/86Sr Compositions of Himalayan River Waters

Stevenson, Emily I.; Burton, Kevin W.; Parkinson, Ian J.; James, Rachael H.; Kisakürek, Basak; Tipper, Ed; Bickle, Michael

Abstract

Silicate weathering on the continents is thought to play a critical part in regulating global climate on geological time scales but determination of the magnitude of silicate weathering fluxes is frustrated by the complexity of the weathering processes. Here we present analyses of stable Sr-isotopic compositions (𝛿88/86Sr) in a suite of river waters and bedloads from the Himalayas in Nepal to establish the lithological controls on 𝛿88/86Sr values and the secondary processes that impact carbonate weathering. A control on 𝛿88/86Sr values is lithology with the rivers in carbonate-dominated catchments marginally lower
‰) than in silicate-dominated catchments. However, as for 87Sr/86Sr ratios, 𝛿88/86Sr values of carbonates are altered by silicate-carbonate mineral exchange during metamorphism. The major potential secondary control on 𝛿88/86Sr values in Himalayan catchments is precipitation of secondary calcite responsible for the marked elevation of Sr/Ca and Mg/Ca ratios in the waters. We re-evaluate the mechanisms for secondary calcite formation and conclude that a balanced solution and re-precipitation process, driven by the relative instability of the primary Mg-rich calcite, provides a better explanation for the elevated Sr/Ca ratios than simple precipitation from a highly over saturated solution. This solution-re-precipitation process is akin to that invoked to explain diagenesis of deep-sea sediments. The mechanism of secondary calcite formation impacts the distinction of cation inputs from carbonate and silicate minerals. The correlation between 𝛿88/86Sr water-calcite fractionations, Sr/Ca partition coefficients and precipitation rates allows the calcite re-precipitation rates to be inferred from the covariation of water 𝛿88/86Sr values and Sr/Ca ratios. These rates are very low (<10-8 mol m-2 s-1) but are consistent with those inferred from field estimates of the amount of calcite re-precipitated, the surface area of carbonate exposed to weathering and the calcite weathering flux. The low precipitation rates are also consistent with previously reported 𝛥44/40Ca isotope fractionations of
‰. The calcite reprecipitation rates are comparable to silicate weathering rates previously inferred from Li-isotopic compositions which is consistent with calcite re-precipitation taking place very close to equilibrium following the initial rapid saturation of the fluids by calcite.

Citation

Stevenson, E. I., Burton, K. W., Parkinson, I. J., James, R. H., Kisakürek, B., Tipper, E., & Bickle, M. (2024). Calcite Dissolution-Reprecipitation Reactions Are a Key Control on the Sr/Ca, Mg/Ca and δ88/86Sr Compositions of Himalayan River Waters. American journal of science (1880), 324, https://doi.org/10.2475/001c.124202

• Journal Article Type: Article
• Acceptance Date: Sep 25, 2024
• Online Publication Date: Nov 4, 2024
• Publication Date: 2024-11
• Deposit Date: Jan 22, 2025
• Publicly Available Date: Jan 22, 2025
• Journal: American Journal of Science
• Print ISSN: 0002-9599
• Electronic ISSN: 1945-452X
• Publisher: American Journal of Science
• Peer Reviewed: Peer Reviewed
• Volume: 324
• DOI: https://doi.org/10.2475/001c.124202
• Public URL: https://durham-repository.worktribe.com/output/3346405