Nonconjugated Polyurethane Derivatives with Aggregation-Induced Luminochromism for Multicolor and White Photoluminescent Films

Jiang, Nan; Meng, Ya-Jie; Zhu, Chang-Yi; Li, Ke-Xin; Li, Xin; Xu, Yan-Hong; Xu, Jia-Wei; Bryce, Martin R.

Abstract

A simple and effective strategy to obtain solid-state multicolor emitting materials is a particularly attractive topic. Nonconventional/nonconjugated polymers are receiving widespread attention because of their advantages of rich structural diversity, low cost, and good processability. However, it is difficult to control the molecular conformation or to obtain the crystal structure of amorphous molecules, which means it is a challenge to obtain nontraditional polymeric materials with multicolor emission. In this work, a polyurethane derivative (PUH) with red-shifted emission was synthesized by a simple one-pot polymerization reaction. By exploiting the aggregation-induced luminochromism of PUH, a series of plastic films with tunable emission from blue to orange, and white-light emission, was obtained by doping different amounts of PUH into poly(methyl methacrylate) (PMMA), thereby changing the aggregation degree of PUH. This work demonstrates the excellent promise of polyurethane derivatives for the simple fabrication of large-scale flexible luminescent films.

Citation

Jiang, N., Meng, Y.-J., Zhu, C.-Y., Li, K.-X., Li, X., Xu, Y.-H., Xu, J.-W., & Bryce, M. R. (2024). Nonconjugated Polyurethane Derivatives with Aggregation-Induced Luminochromism for Multicolor and White Photoluminescent Films. ACS Macro Letters, 13(10), 1226-1232. https://doi.org/10.1021/acsmacrolett.4c00534

• Journal Article Type: Article
• Acceptance Date: Sep 4, 2024
• Online Publication Date: Sep 9, 2024
• Publication Date: Oct 15, 2024
• Deposit Date: Sep 13, 2024
• Publicly Available Date: Sep 13, 2024
• Journal: ACS Macro Letters
• Electronic ISSN: 2161-1653
• Publisher: American Chemical Society
• Peer Reviewed: Peer Reviewed
• Volume: 13
• Issue: 10
• Pages: 1226-1232
• DOI: https://doi.org/10.1021/acsmacrolett.4c00534
• Public URL: https://durham-repository.worktribe.com/output/2863271