In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes

Goodall, Joe C.; Page, Samuel J.; Sajjad, M. Arif; Thompson, Emily A.; Kerrigan, Adam M.; Jenkins, Huw T.; Lynam, Jason M.; Macgregor, Stuart A.; Weller, Andrew S.

Abstract

The group 7 complexes [M(κ3-2,6-(R2PO)2C5H3N)(CO)2L][BArF4] [M = Mn, R = iPr, L = THF; M = Re, R = tBu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is a large, local, adaptive change of [BArF4] anions for M = Mn, whereas for M = Re the changes are smaller and also remote to the site of reactivity.

Citation

Goodall, J. C., Page, S. J., Sajjad, M. A., Thompson, E. A., Kerrigan, A. M., Jenkins, H. T., …Weller, A. S. (2023). In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes. Chemical Communications, 59(72), 10749-10752. https://doi.org/10.1039/d3cc03201a

• Journal Article Type: Article
• Acceptance Date: Aug 2, 2023
• Online Publication Date: Aug 7, 2023
• Publication Date: 2023
• Deposit Date: Nov 6, 2023
• Publicly Available Date: Nov 6, 2023
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 59
• Issue: 72
• Pages: 10749-10752
• DOI: https://doi.org/10.1039/d3cc03201a
• Keywords: Materials Chemistry; Metals and Alloys; Surfaces, Coatings and Films; General Chemistry; Ceramics and Composites; Electronic, Optical and Magnetic Materials; Catalysis
• Public URL: https://durham-repository.worktribe.com/output/1898389