Synthesis, structure and optical characterisation of silicon phthalocyanine bis-esters

Farren, C.; FitzGerald, S.; Bryce, M.R.; Beeby, A.; Batsanov, A.S.

Abstract

A range of axially substituted silicon phthalocyanines has been synthesised using various carboxylates as the ligands. 4-tert-Butylbenzoic acid gives rigid, orthogonal axial substituents, whilst a thiophene-containing bis-acetate was conformationally more flexible. Varying the aromatic substituents of phenylacetic acids gave phthalocyanines with altered spectroscopic properties, and changes in the alkyl chain length between the phthalocyanine and the aromatic nucleus of the ligand induced variations in the fluorescence lifetime and quantum yield. Three X-ray crystal structures of axially substituted silicon phthalocyanine bis-esters have been determined.

Citation

Farren, C., FitzGerald, S., Bryce, M., Beeby, A., & Batsanov, A. (2002). Synthesis, structure and optical characterisation of silicon phthalocyanine bis-esters. Journal of the Chemical Society-Perkin Transactions 2, 59-66

• Journal Article Type: Article
• Publication Date: 2002-01
• Journal: Journal of the Chemical Society, Perkin Transactions 2
• Print ISSN: 1470-1820
• Peer Reviewed: Peer Reviewed
• Issue: 1
• Pages: 59-66