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Synthesis of conjugated tetrathiafulvalene (TTF)-pi-acceptor molecules - Intramolecular charge transfer and nonlinear optical properties

Bryce, M.R.; Green, A.; Moore, A.J.; Perepichka, D.F.; Batsanov, A.S.; Howard, J.A.K.; Ledoux-Rak, I.; Gonzalez, M.; Martin, N.; Segura, J.L.; Garin, J.; Orduna, J.; Alcala, R.; Villacampa, B.

Authors

A. Green

A.J. Moore

D.F. Perepichka

I. Ledoux-Rak

M. Gonzalez

N. Martin

J.L. Segura

J. Garin

J. Orduna

R. Alcala

B. Villacampa



Abstract

We have synthesised new conjugated donor-pi -acceptor (D-pi -A) chromophores 7, 9, and 12-15 in which monosubstituted tetrathiafulvalene (TTF) and trimethyl-TTF units are the donor moieties, connected by ethylenic bridges to electron-deficient benzene derivatives as the acceptor moieties. These compounds display a broad intramolecular charge transfer (ICT) band in their solution UV/Vis spectra at lambda (max) = ca.

Citation

Bryce, M., Green, A., Moore, A., Perepichka, D., Batsanov, A., Howard, J., …Villacampa, B. (2001). Synthesis of conjugated tetrathiafulvalene (TTF)-pi-acceptor molecules - Intramolecular charge transfer and nonlinear optical properties. European Journal of Organic Chemistry, 1927-1935

Journal Article Type Article
Publication Date 2001-05
Journal European Journal of Organic Chemistry
Print ISSN 1434-193X
Publisher Wiley
Peer Reviewed Peer Reviewed
Issue 10
Pages 1927-1935
Publisher URL <Go to ISI>://000168800100016