A new synthetic route to [MF(mu-F)(CO)(3)](4) (M = Ru, Os) and their reactivity with P(C6H4-4-X)(3) (X = OCH3, OH) and P(C6H4-2-OH)(3) -Crystal structure of [OS(CO)(3){kappa(3)-(2-OC6H4)(2)P(C6H4-2-OH)}]center dot C3H6O

Coleman, KS; Fawcett, J; Holloway, JH; Hope, EG; Nassar, R

Abstract

The reaction of [M-3(CO)(12)] (M = Ru, Os) with elemental fluorine in anhydrous HF offers a clean, convenient route to [MF(mu -F)(CO)(3)](4). This tetramer reacts with Tris-ortho-hydroxyphenyl phosphine, with the elimination of HF, to give a new, metal-bound, trihapto (eta (3)-P,O,O) ligand. (C) 2001 Elsevier Science B.V. All rights reserved.

Citation

Coleman, K., Fawcett, J., Holloway, J., Hope, E., & Nassar, R. (2001). A new synthetic route to [MF(mu-F)(CO)(3)](4) (M = Ru, Os) and their reactivity with P(C6H4-4-X)(3) (X = OCH3, OH) and P(C6H4-2-OH)(3) -Crystal structure of [OS(CO)(3){kappa(3)-(2-OC6H4)(2)P(C6H4-2-OH)}]center dot C3H6O. Journal of Fluorine Chemistry, 112(2), 185-189. https://doi.org/10.1016/s0022-1139%2801%2900509-7

• Journal Article Type: Article
• Publication Date: 2001-12
• Journal: Journal of Fluorine Chemistry
• Print ISSN: 0022-1139
• Electronic ISSN: 1873-3328
• Publisher: Elsevier
• Peer Reviewed: Peer Reviewed
• Volume: 112
• Issue: 2
• Pages: 185-189
• DOI: https://doi.org/10.1016/s0022-1139%2801%2900509-7
• Keywords: tris-ortho-hydroxyphenyl phosphine; tris-para-hydroxyphenyl phosphine;triosmium-dodecacarbonyl; metal fluorideAROMATIC PHOSPHINES; CARBONYL FLUORIDES; METAL-COMPLEXES; METHOXY GROUPS
• Public URL: https://durham-repository.worktribe.com/output/1576458