A cross-coupling strategy for the synthesis of dimetallic assemblies containing mixed bipyridine–terpyridine bridging ligands: luminescence and energy transfer properties.

Arm, K.J.; Williams, J.A.G.

Abstract

Tris-bidentate complexes of the form [Ir(N^C)2(N^N)]+ and [Ru(N^N)3]2+ incorporating a boronic acid substituent (N^C = 2-phenylpyridyl, N^N = a 2,2′-bipyridyl ligand), are cross-coupled with bromo-substituted bis-terpyridyl ruthenium and iridium complexes to generate heterometallic assemblies comprising bpy-ϕn-tpy bridges; they display efficient energy transfer from Ir(III) to Ru(II).

Citation

Arm, K., & Williams, J. (2006). A cross-coupling strategy for the synthesis of dimetallic assemblies containing mixed bipyridine–terpyridine bridging ligands: luminescence and energy transfer properties. Dalton Transactions, 2006(18), 2172-2174. https://doi.org/10.1039/b602022d

• Journal Article Type: Article
• Acceptance Date: Mar 9, 2006
• Online Publication Date: Mar 24, 2006
• Publication Date: 2006
• Journal: Dalton Transactions
• Print ISSN: 1477-9226
• Electronic ISSN: 1477-9234
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 2006
• Issue: 18
• Pages: 2172-2174
• DOI: https://doi.org/10.1039/b602022d
• Public URL: https://durham-repository.worktribe.com/output/1575321