Skip to main content

Research Repository

Advanced Search

A cross-coupling strategy for the synthesis of dimetallic assemblies containing mixed bipyridine–terpyridine bridging ligands: luminescence and energy transfer properties.

Arm, K.J.; Williams, J.A.G.

Authors

K.J. Arm



Abstract

Tris-bidentate complexes of the form [Ir(N^C)2(N^N)]+ and [Ru(N^N)3]2+ incorporating a boronic acid substituent (N^C = 2-phenylpyridyl, N^N = a 2,2′-bipyridyl ligand), are cross-coupled with bromo-substituted bis-terpyridyl ruthenium and iridium complexes to generate heterometallic assemblies comprising bpy-ϕn-tpy bridges; they display efficient energy transfer from Ir(III) to Ru(II).

Citation

Arm, K., & Williams, J. (2006). A cross-coupling strategy for the synthesis of dimetallic assemblies containing mixed bipyridine–terpyridine bridging ligands: luminescence and energy transfer properties. Dalton Transactions, 2172-2174. https://doi.org/10.1039/b602022d

Journal Article Type Article
Acceptance Date Mar 9, 2006
Online Publication Date Mar 24, 2006
Publication Date 2006
Journal Dalton Transactions
Print ISSN 1477-9226
Electronic ISSN 1477-9234
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Issue 18
Pages 2172-2174
DOI https://doi.org/10.1039/b602022d