Synthesis, characterization and crystal structure of a novel Ni(II) complex, Ni(L-H)(2) (L=3,5-dimethyl-1-thiocarboxamidopyrazole)

Evans, I.R.; Howard, J.A.K.; Szecsenyi, K.M.; Leovac, V.M.; Jacimovic, Z.K.

Abstract

A new complex, Ni(L-H)(2), L = 3,5-dimethyl-1-thiocarboxamidopyrazole, has been synthesized and characterized by IR spectroscopy, magnetic and electrical measurements. Its crystal structure was solved from powder X-ray diffraction data. The compound crystallizes in space group P (1) over bar with two independent half-molecules containing Ni(II) coordinated by four nitrogen atoms in a square-plane. The packing pattern consists of two stacks of parallel molecules mutually tilted at an angle of 118degrees.

Citation

Evans, I., Howard, J., Szecsenyi, K., Leovac, V., & Jacimovic, Z. (2004). Synthesis, characterization and crystal structure of a novel Ni(II) complex, Ni(L-H)(2) (L=3,5-dimethyl-1-thiocarboxamidopyrazole). Journal of Coordination Chemistry, 57(6), 469-476

• Journal Article Type: Article
• Publication Date: 2004-04
• Journal: Journal of Coordination Chemistry
• Print ISSN: 0095-8972
• Electronic ISSN: 1029-0389
• Publisher: Taylor and Francis Group
• Peer Reviewed: Peer Reviewed
• Volume: 57
• Issue: 6
• Pages: 469-476
• Public URL: https://durham-repository.worktribe.com/output/1570431