C.A. Ilioudis
Complexation of I-4(2-) and I-8(2-) by protonated azacyclophanes
Ilioudis, C.A.; Steed, J.W.
Abstract
A macrocyclic azacyclophane (1) includes two iodide anions within its macrocyclic cavity. The resulting 1 . 2I(-) complex ( in two polymorphic modifications) sandwiches I-2 in the solid state to give a 'complex of complexes' effectively stabilising the rare I-4(2-) anion. A third crystal form contains a macrocycle incorporating both a discrete I- anion and the tail of the polymeric I-8(2-) in a closely related fashion.
Citation
Ilioudis, C., & Steed, J. (2004). Complexation of I-4(2-) and I-8(2-) by protonated azacyclophanes. CrystEngComm, 6, 239-242
Journal Article Type | Article |
---|---|
Publication Date | 2004-07 |
Journal | CrystEngComm |
Electronic ISSN | 1466-8033 |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
Volume | 6 |
Pages | 239-242 |
Public URL | https://durham-repository.worktribe.com/output/1570174 |
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