R.L. Giles
Synthesis and structure of potential Lewis acid-Lewis base bifunctional catalysts: 1-N,N-dimethylamino-8-borononaphthalene derivatives
Giles, R.L.; Howard, J.A.K.; Patrick, L.G.F.; Probert, M.R.; Smith, G.E.; Whiting, A.
Authors
Judith Howard j.a.k.howard@durham.ac.uk
Emeritus Professor
L.G.F. Patrick
M.R. Probert
G.E. Smith
Andrew Whiting andy.whiting@durham.ac.uk
Emeritus Professor
Abstract
A new series of boronate-amine substituted potential bifunctional catalysts have been prepared by directed lithiation of 1-N,N-dimethylnaphthalene, followed by reaction borate esters. Both diisopropyl and pincacol ester derivatives of the resulting boronates were prepared, together with a novel boroxine which shows novel N-B interactions in the crystal structure. The corresponding dimethyl-[8-(difluoroborolyl)-naphthalen-1-yl]-amine was directly accessed from the boroxine by reaction with potassium hydrogen fluoride. (C) 2003 Elsevier Science B.V. All rights reserved.
Citation
Giles, R., Howard, J., Patrick, L., Probert, M., Smith, G., & Whiting, A. (2003). Synthesis and structure of potential Lewis acid-Lewis base bifunctional catalysts: 1-N,N-dimethylamino-8-borononaphthalene derivatives. Journal of Organometallic Chemistry, 680(1-2), 257-262
Journal Article Type | Article |
---|---|
Publication Date | 2003-08 |
Journal | Journal of Organometallic Chemistry |
Print ISSN | 0022-328X |
Publisher | Elsevier |
Peer Reviewed | Peer Reviewed |
Volume | 680 |
Issue | 1-2 |
Pages | 257-262 |
Public URL | https://durham-repository.worktribe.com/output/1570122 |
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