Magma–Carbonate Interaction Processes and Associated CO2 Release at Merapi Volcano, Indonesia: Insights from Experimental Petrology

Deegan, F.M.; Troll, V.R.; Freda, C.; Misiti, V.; Chadwick, J.P.; McLeod, C.L.; Davidson, J.P.

Abstract

There is considerable evidence for ongoing, late-stage interaction between the magmatic system at Merapi volcano, Indonesia, and local crustal carbonate (limestone). Calc-silicate xenoliths within Merapi basaltic-andesite eruptives display textures indicative of intense interaction between magma and crustal carbonate, and Merapi feldspar phenocrysts frequently contain individual crustally contaminated cores and zones. In order to resolve the interaction processes between magma and limestone in detail we have performed a series of time-variable de-carbonation experiments in silicate melt, at magmatic pressure and temperature, using a Merapi basaltic-andesite and local Javanese limestone as starting materials. We have used in-situ analytical methods to determine the elemental and strontium isotope composition of the experimental products and to trace the textural, chemical, and isotopic evolution of carbonate assimilation. The major processes of magmacarbonate interaction identified are: i) rapid decomposition and degassing of carbonate, ii) generation of a Ca-enriched, highly radiogenic strontium contaminant melt, distinct from the starting material composition, iii) intense CO2 vesiculation, particularly within the contaminated zones, iv) physical mingling between the contaminated and unaffected melt domains, and v) chemical mixing between melts. The experiments reproduce many of the features of magmacarbonate interaction observed in the natural Merapi xenoliths and feldspar phenocrysts. The Carich, high 87Sr/86Sr contaminant melt produced in the experiments is considered as a pre-cursor to the Ca-rich (often “hyper-calcic”) phases found in the xenoliths and the contaminated zones in Merapi feldspars. The xenoliths also exhibit micro-vesicular textures which can be linked to the CO2 liberation process seen in the experiments. This study, therefore, provides well-constrained petrological insights into the problem of crustal interaction at Merapi and points toward the substantial impact of such interaction on the volatile budget of the volcano.

Citation

Deegan, F., Troll, V., Freda, C., Misiti, V., Chadwick, J., McLeod, C., & Davidson, J. (2010). Magma–Carbonate Interaction Processes and Associated CO2 Release at Merapi Volcano, Indonesia: Insights from Experimental Petrology. Journal of Petrology, 51(5), 1027-1051. https://doi.org/10.1093/petrology/egq010

• Journal Article Type: Article
• Publication Date: May 1, 2010
• Deposit Date: Jun 21, 2010
• Publicly Available Date: Mar 1, 2013
• Journal: Journal of Petrology
• Print ISSN: 0022-3530
• Electronic ISSN: 1460-2415
• Publisher: Oxford University Press
• Peer Reviewed: Peer Reviewed
• Volume: 51
• Issue: 5
• Pages: 1027-1051
• DOI: https://doi.org/10.1093/petrology/egq010
• Keywords: Carbon dioxide, Experimental petrology, Magma–carbonate interaction, Merapi, Strontium isotopes.
• Public URL: https://durham-repository.worktribe.com/output/1543696
• Publisher URL: http://petrology.oxfordjournals.org/cgi/content/full/51/5/1027