The intramolecular β-fluorine⋯ammonium interaction in 4- and 8-membered rings.

Gooseman, N.E.J.; O'Hagan, D.; Slawin, A.M.Z.; Teale, A.M.; Tozer, D.J.; Young, R.J.

doi:10.1039/b606334a

The intramolecular β-fluorine⋯ammonium interaction in 4- and 8-membered rings.

Gooseman, N.E.J.; O'Hagan, D.; Slawin, A.M.Z.; Teale, A.M.; Tozer, D.J.; Young, R.J.

Authors

N.E.J. Gooseman

D. O'Hagan

A.M.Z. Slawin

A.M. Teale

Professor David Tozer d.j.tozer@durham.ac.uk
Professor

R.J. Young

Abstract

The structures of 3-fluoroazetidinium hydrochloride and 3-fluoro-1,5-diazacyclooctane hydrobromide are explored both by X-ray diffraction analysis and DFT calculations, and the conformations of these molecules are shown to be significantly influenced by the through space C–F⋯N+ interaction.

Citation

Gooseman, N., O'Hagan, D., Slawin, A., Teale, A., Tozer, D., & Young, R. (2006). The intramolecular β-fluorine⋯ammonium interaction in 4- and 8-membered rings. Chemical Communications, 2006(30), 3190-3192. https://doi.org/10.1039/b606334a

Journal Article Type	Article
Acceptance Date	May 26, 2006
Online Publication Date	Jun 21, 2006
Publication Date	2006
Journal	Chemical Communications
Print ISSN	1359-7345
Electronic ISSN	1364-548X
Publisher	Royal Society of Chemistry
Peer Reviewed	Peer Reviewed
Volume	2006
Issue	30
Pages	3190-3192
DOI	https://doi.org/10.1039/b606334a
Public URL	https://durham-repository.worktribe.com/output/1542210