The preparation and characterisation of ruthenium cyanovinylidene complexes.

Brown, Neil J.; Eckert, Prisca K.; Fox, Mark A.; Yufit, Dmitri S.; Howard, Judith A.K.; Low, Paul J.

Abstract

Reactions of half-sandwich ruthenium metal acetylide complexes with 1-cyano-4-dimethylaminopyridinium salts afford complexes containing mono- or di-cyanovinylidene ligands; the procedure can be adapted to permit the simple synthesis of a cyanoacetylide complex, via the in situ deprotonation of a primary cyanovinylidene complex.

Citation

Brown, N. J., Eckert, P. K., Fox, M. A., Yufit, D. S., Howard, J. A., & Low, P. J. (2008). The preparation and characterisation of ruthenium cyanovinylidene complexes. Dalton Transactions, 2008(4), 433-436. https://doi.org/10.1039/b714274a

• Journal Article Type: Article
• Acceptance Date: Oct 23, 2007
• Online Publication Date: Nov 8, 2007
• Publication Date: 2008
• Deposit Date: Dec 14, 2011
• Journal: Dalton Transactions
• Print ISSN: 1477-9226
• Electronic ISSN: 1477-9234
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 2008
• Issue: 4
• Pages: 433-436
• DOI: https://doi.org/10.1039/b714274a
• Public URL: https://durham-repository.worktribe.com/output/1524302