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Stable Polymorphs Crystallized Directly under Thermodynamic Control in Three-Dimensional Nanoconfinement: A Generic Methodology

Nicholson, CE; Chen, C; Mendis, B; Cooper, SJ

Stable Polymorphs Crystallized Directly under Thermodynamic Control in Three-Dimensional Nanoconfinement: A Generic Methodology Thumbnail


Authors

CE Nicholson

C Chen



Abstract

Thermodynamic control of crystallization has been achieved to produce stable polymorphs directly by using three-dimensional (3D) nanoconfinement in microemulsions. The theoretical basis for thermodynamic control of crystallization using 3D nanoconfinement is outlined. The generality of our approach is demonstrated by crystallizing the stable polymorph of three “problem” compounds from microemulsions under conditions yielding metastable forms in bulk solution.

Citation

Nicholson, C., Chen, C., Mendis, B., & Cooper, S. (2011). Stable Polymorphs Crystallized Directly under Thermodynamic Control in Three-Dimensional Nanoconfinement: A Generic Methodology. Crystal Growth and Design, 11(2), 363-366. https://doi.org/10.1021/cg101200f

Journal Article Type Article
Online Publication Date Jan 5, 2011
Publication Date Jan 5, 2011
Deposit Date Jan 30, 2012
Publicly Available Date Sep 12, 2017
Journal Crystal Growth and Design
Print ISSN 1528-7483
Electronic ISSN 1528-7505
Publisher American Chemical Society
Peer Reviewed Peer Reviewed
Volume 11
Issue 2
Pages 363-366
DOI https://doi.org/10.1021/cg101200f
Public URL https://durham-repository.worktribe.com/output/1519474

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Accepted Journal Article (693 Kb)
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Copyright Statement
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Crystal growth & design, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/cg101200f






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