Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(ii)–Re(i) complex

Smith, Mark E.; Flynn, Emma L.; Fox, Mark A.; Trottier, Alexandre; Wrede, Eckart; Yufit, Dmitri S.; Howard, Judith A.K.; Ronayne, Kate L.; Towrie, Michael; Parker, Anthony W.; Hartl, František; Low, Paul J.

Abstract

Photoinduced Fe-to-bpy charge transfer in [{Cp(dppe)Fe}(μ-C[triple bond, length as m-dash]CC[triple bond, length as m-dash]N){Re(CO)3(bpy)}]PF6 has been observed by ps-TRIR spectroscopy, supported by UV-Vis/IR spectroelectrochemistry and DFT calculations.

Citation

Smith, M. E., Flynn, E. L., Fox, M. A., Trottier, A., Wrede, E., Yufit, D. S., …Low, P. J. (2008). Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(ii)–Re(i) complex. Chemical Communications, 5845-5847. https://doi.org/10.1039/b811357b

• Journal Article Type: Article
• Acceptance Date: Aug 28, 2008
• Online Publication Date: Oct 7, 2008
• Publication Date: 2008-11
• Deposit Date: Dec 14, 2011
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Issue: 44
• Pages: 5845-5847
• DOI: https://doi.org/10.1039/b811357b