Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(ii)–Re(i) complex

Smith, Mark E.; Flynn, Emma L.; Fox, Mark A.; Trottier, Alexandre; Wrede, Eckart; Yufit, Dmitri S.; Howard, Judith A.K.; Ronayne, Kate L.; Towrie, Michael; Parker, Anthony W.; Hartl, František; Low, Paul J.

Abstract

Photoinduced Fe-to-bpy charge transfer in [{Cp(dppe)Fe}(μ-C[triple bond, length as m-dash]CC[triple bond, length as m-dash]N){Re(CO)3(bpy)}]PF6 has been observed by ps-TRIR spectroscopy, supported by UV-Vis/IR spectroelectrochemistry and DFT calculations.

Citation

Smith, M. E., Flynn, E. L., Fox, M. A., Trottier, A., Wrede, E., Yufit, D. S., Howard, J. A., Ronayne, K. L., Towrie, M., Parker, A. W., Hartl, F., & Low, P. J. (2008). Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(ii)–Re(i) complex. Chemical Communications, 2008(44), 5845-5847. https://doi.org/10.1039/b811357b

• Journal Article Type: Article
• Acceptance Date: Aug 28, 2008
• Online Publication Date: Oct 7, 2008
• Publication Date: Nov 30, 2008
• Deposit Date: Dec 14, 2011
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 2008
• Issue: 44
• Pages: 5845-5847
• DOI: https://doi.org/10.1039/b811357b
• Public URL: https://durham-repository.worktribe.com/output/1501096