CE Willans
Deboronation and Deprotonation of ortho-Carborane with N-Heterocyclic Carbenes
Willans, CE; Kilner, CA; Fox, MA
Abstract
It is a matter of size: N-Heterocyclic carbenes can remove a proton from ortho-carborane to form a two-cage anion or attack the electropositive boron of ortho-carborane to yield a stable 1:2 carborane–carbene adduct. Which end product is formed depends on the steric bulk of the alkyl groups attached to the nitrogen atoms of the carbene.
Citation
Willans, C., Kilner, C., & Fox, M. (2010). Deboronation and Deprotonation of ortho-Carborane with N-Heterocyclic Carbenes. Chemistry - A European Journal, 16(35), 10644-10648. https://doi.org/10.1002/chem.201001730
Journal Article Type | Article |
---|---|
Publication Date | Sep 17, 2010 |
Deposit Date | Dec 14, 2011 |
Journal | Chemistry - A European Journal |
Print ISSN | 0947-6539 |
Electronic ISSN | 1521-3765 |
Publisher | Wiley |
Peer Reviewed | Peer Reviewed |
Volume | 16 |
Issue | 35 |
Pages | 10644-10648 |
DOI | https://doi.org/10.1002/chem.201001730 |
Keywords | Cage compounds, Carboranes, Cluster compounds, N-heterocyclic carbenes. |
Public URL | https://durham-repository.worktribe.com/output/1501070 |
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