Overcoming the solvation shell during the crystallisation of diatrizoic acid from dimethylsulfoxide

Fucke, K.; Howard, J.A.K.; Steed, J.W.

Abstract

We present three crystal structures of diatrizoic acid (DTA) DMSO solvates illustrating progressive desolvation of the DTA molecule and concomitant increasing degree of DTA self-association. Using these structures, plausible pathways for overcoming the solvation shell of DTA during its crystallisation from solution are discussed.

Citation

Fucke, K., Howard, J., & Steed, J. (2012). Overcoming the solvation shell during the crystallisation of diatrizoic acid from dimethylsulfoxide. Chemical Communications, 48(99), 12065-12067. https://doi.org/10.1039/c2cc35995b

• Journal Article Type: Article
• Publication Date: Dec 1, 2012
• Deposit Date: Mar 27, 2013
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 48
• Issue: 99
• Pages: 12065-12067
• DOI: https://doi.org/10.1039/c2cc35995b
• Public URL: https://durham-repository.worktribe.com/output/1461922