A.M. Todd
Anion receptor coordination tripods capped by [9]ane-S3
Todd, A.M.; Swinburne, A.N.; Goeta, A.E.; Steed, J.W.
Abstract
A series of ruthenium(II) complexes with face-capping [9]ane-S3 ligands are described. The compounds function as supramolecular receptors for anions via three tripodally arranged 3-aminopyridine ligands. The [9]ane-S3 ligand stabilises the tripodal complexes which are more readily prepared and studied than their π-arene ruthenium(II) analogues. Pyrenyl derivative 4 displays some activity as a photophysical anion sensor but the anion response is complicated by the complexes concentration dependent emission behaviour. The receptors bind common anions in relatively polar media forming both 1:1 and 1:2 host–anion complexes with the CHanion interactions involving the thioether ring being implicated in anion binding as well as the convention NH donors.
Citation
Todd, A., Swinburne, A., Goeta, A., & Steed, J. (2013). Anion receptor coordination tripods capped by [9]ane-S3. New Journal of Chemistry, 37(1), 89-96. https://doi.org/10.1039/c2nj40401j
Journal Article Type | Article |
---|---|
Publication Date | Jan 1, 2013 |
Deposit Date | Mar 27, 2013 |
Publicly Available Date | Apr 11, 2013 |
Journal | New Journal of Chemistry |
Print ISSN | 1144-0546 |
Electronic ISSN | 1369-9261 |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
Volume | 37 |
Issue | 1 |
Pages | 89-96 |
DOI | https://doi.org/10.1039/c2nj40401j |
Public URL | https://durham-repository.worktribe.com/output/1459981 |
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